389086-22-0

Upstream product

• 389086-21-9 (2E,4R,5S,6S)-N-methoxy-N-methyl-4-(tert-butyldimethylsilyl)oxy-7-(tert-butyldiphenylsilyl)oxy-5,6-(dimethylmethylenedioxy)-2-heptenamide 
• 74-88-4 methyl iodide 
• 389086-20-8 (2E,4R,5S,6S)-N-methoxy-N-methyl-4-(tert-butyldimethylsilyl)oxy-5,6-(dimethylmethylenedioxy)-7-hydroxy-2-heptenamide 
• 389086-19-5 (3aS,6S,7S,7aS)-6-benzyloxy-2,2-dimethyl-7-(tert-butyldimethylsilyl)oxy-tetrahydro-1,3-dioxolo[4,5-c]pyran 
• 75921-31-2 2-O-(t-butyldimethylsilyl)-3,4-O-isopropylidene-L-ribopyranose 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 26685-74-5 1-O-benzyl-3,4-O-isopropylidene-β-L-ribopyranose 

Downstream Products

• 389086-14-0 C₇₉H₁₃₀O₁₁S₂Si₄ 
• 389085-95-4 (4R,5R,6S,7S)-5-(tert-butyldimethylsilyl)oxy-8-(tert-butyldiphenylsilyl)oxy-5,6-(dimethylmethylenedioxy)-4-methylocten-2-one 

Relevant academic research and scientific papers

A highly stereoselective synthesis of the C10-C31 (BCDEF ring) portion of pinnatoxin A

An efficient, highly stereoselective synthesis of the C10-C31 (BCDEF ring) portion of pinnatoxin A has been achieved utilizing tandem double hemiketal formation/intramolecular hetero-Michael addition to construct the 6,5,6-dispiroketal (BCD ring) system a