38965-61-6

Basic information

• Product Name: (4S)-4,5-Dihydro-4α-hydroxy-5β-methyl-3-[(Z)-tetradecan-1-ylidene]furan-2(3H)-one
• Synonyms: (4S)-4,5-Dihydro-4α-hydroxy-5β-methyl-3-[(Z)-tetradecan-1-ylidene]furan-2(3H)-one;Litsenolide C1
• CAS NO: 38965-61-6
• Molecular Formula: C19H34O3
• Molecular Weight: 310.47146
• Mol File: 38965-61-6.mol
• Article Data: 8

Chemical Properties

• Appearance: /
• CAS DataBase Reference: (4S)-4,5-Dihydro-4α-hydroxy-5β-methyl-3-[(Z)-tetradecan-1-ylidene]furan-2(3H)-one(CAS DataBase Reference)
• NIST Chemistry Reference: (4S)-4,5-Dihydro-4α-hydroxy-5β-methyl-3-[(Z)-tetradecan-1-ylidene]furan-2(3H)-one(38965-61-6)
• EPA Substance Registry System: (4S)-4,5-Dihydro-4α-hydroxy-5β-methyl-3-[(Z)-tetradecan-1-ylidene]furan-2(3H)-one(38965-61-6)

Safety Data

• Hazardous Substances Data: 38965-61-6(Hazardous Substances Data)

Upstream product

• 25966-39-6 3-bromo-5-methyldihydrofuran-2(3H)-one 
• 78277-66-4 <(+/-)-(3E,4α,5α)>-4-hydroxy-5-((phenylselenenyl)methyl)-3-tetradecylidenetetrahydro-2-furanone 
• 111954-40-6 2-phenylthio-2-tetradecanyl-3-hydroxy-4-valerolactone 
• 111722-90-8 2-[(1R,2R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-hydroxy-propyl]-2-phenylsulfanyl-hexadecanoic acid methyl ester 
• 111954-39-3 2-phenylthio-2-tetradecanyl-3-hydroxy-4-valerolactone 
• 111722-90-8 2-[(1S,2R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-hydroxy-propyl]-2-phenylsulfanyl-hexadecanoic acid methyl ester 
• 111900-38-0 (3R,4S,5R)-3-Benzenesulfinyl-4-hydroxy-5-methyl-3-tetradecyl-dihydro-furan-2-one 
• 111900-40-4 (3R,4R,5R)-3-Benzenesulfinyl-4-hydroxy-5-methyl-3-tetradecyl-dihydro-furan-2-one 
• 78277-46-0 methyl 2-phenylselenenylhexadecanoate 
• 78277-57-3 (E)-2-(1-Hydroxy-allyl)-hexadec-2-enoic acid 
• 112-39-0 hexadecanoic acid methyl ester 
• 78301-20-9 <(+/-)-(3E,4α,5α)>-4-hydroxy-5-(iodomethyl)-3-tetradecylidenetetrahydro-2-furanone 
• 112-71-0 1-Bromotetradecane 
• 75938-47-5 Methanesulfonic acid 1-(5-methyl-2-oxo-2,5-dihydro-furan-3-yl)-tetradecyl ester 

Relevant articles and documents

Asymmetric synthesis of α-alkylidene-β-hydroxy-γ- butyrolactones via enantioselective tandem michael-aldol reaction

A simple and efficient method for the asymmetric synthesis of α-alkylidene-β-hydroxy-γ-butyrolactones and related natural products was developed on the basis of the catalytic asymmetric tandem Michael-aldol reaction and simple transformations. The synthetic utility of this method was illustrated by the facile synthesis of trisubstituted γ-butyrolactone natural products.

The Total Synthesis of (-)-Litsenolides C-1 and C-2

The total synthesis of (-)-litsenolides C1 and C2 from D-glucose in 12percent overall yield is described in which the α-alkylidene double-bond is formed by a Wittig reaction of a C-2 oxocarbohydrate derivative.

The use of D-ribonolactone in organic synthesis. I. Total synthesis of (-)-litsenolides C1 and C2

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