389811-95-4

Basic information

• Product Name: Silane, [3-(4-bromophenyl)propoxy](1,1-dimethylethyl)diphenyl-
• CAS NO: 389811-95-4
• Molecular Formula: C25H29BrOSi
• Molecular Weight: 453.494
• Mol File: 389811-95-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Silane, [3-(4-bromophenyl)propoxy](1,1-dimethylethyl)diphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [3-(4-bromophenyl)propoxy](1,1-dimethylethyl)diphenyl-(389811-95-4)
• EPA Substance Registry System: Silane, [3-(4-bromophenyl)propoxy](1,1-dimethylethyl)diphenyl-(389811-95-4)

Safety Data

• Hazardous Substances Data: 389811-95-4(Hazardous Substances Data)

Upstream product

• 25574-11-2 3-(4-bromophenyl)propanol 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Downstream Products

• 389811-99-8 3-(4-triphenylmethyloxymethylphenyl)propyloxy-tert-butyldiphenylsilane 
• 389811-88-5 3-(4-triphenylmethyloxymethylphenyl)propanol 

Relevant articles and documents

Solid-phase synthesis of a branched hexasaccharide using a highly efficient synthetic strategy

The solid-phase synthesis of branched lacto-N-neohexaose derivative 1 occurring in human milk is described. The new building block of lactose 3 bearing the orthogonal temporary hydroxy protecting groups 9-fluorenylmethyloxycarbonyl (Fmoc) and levulinoyl (Lev) has been prepared. Its use, together with that of lactosamine donor 4, glucosamine donor 5, and O-galactosyl trichloroacetimidate 6, has enabled the preparation of hexasaccharide 22 following two different approaches in excellent overall yield (43%, 90% per step over eight steps). An additional key feature of this work is the successful use of newly prepared ester-type linker 2, having a benzylic spacer connected to the anomeric oxygen. This linker presents the advantage of producing a benzylic anomeric moiety after cleavage from the polymer support, which could be easily removed to obtain the unprotected oligosaccharide 1.