38987-28-9Relevant academic research and scientific papers
THE REACTIONS OF Δ3-PHOSPHOLENES WITH SULPHENATE ESTERS AND SULPHENAMIDES
Hammond, Philip J.,Lloyd, John R.,Hall, C. Dennis
, p. 67 - 80 (2007/10/02)
The reactions of 1-methyl and 1-phenyl-Δ3-phospholenes with sulphenate esters give rise to a range of products involving rearrangement of the endocyclic double bond, dealkylation to phospholene oxides and fragmentation of the ring.When reacted with N,N-diethyl methylsulphenamide, the same phospholenes give ylids by loss of a proton from position-2 or 5 of an intermediate phospholenium amide.
