390432-39-0Relevant academic research and scientific papers
Synthesis and reactions with carbon dioxide of mono(σ-alkynyl) titanocene(III) complexes Cp*2Ti(C≡CR) (R = Me, t-Bu) and the corresponding "Ate" complexes [Cp*2Ti(C≡CR)2Li(THF)n] (R = SiMe3, t-Bu, Ph)
Kirchbauer, Frank G.,Pellny, Paul-Michael,Sun, Hongsui,Burlakov, Vladimir V.,Arndt, Perdita,Baumann, Wolfgang,Spannenberg, Anke,Rosenthal, Uwe
, p. 5289 - 5296 (2008/10/08)
The reactions of the titanium(III) complex Cp*2TiCl with lithium acetylides RC≡CLi depend strongly on the solvents used. In THF only the lithium tweezer compounds [Cp*2-Ti(C≡CR)2Li(THF)n] (Cp* = η5-C
