39082-23-0Relevant academic research and scientific papers
Synthesis and crystal structure of Hf2Te
Harbrecht,Conrad,Degen,Herbertz
, p. 178 - 182 (1997)
Hf2Te was prepared by arc-melting appropriate compressed mixtures of HfTe2 and hafnium. The structure of the new hafnium-rich telluride was determined by means of powder diffractometry, RB=0.0565. Hf2Te adopts a Nb2Se-type structure, monoclinic, space group C2/m, Z=8, Pearson symbol mS24, a= 1516.3(2) pm, b=370.26(4) pm, c= 1006.4(1) pm, β=90.50(1)°. The structure comprises pairwise interpenetrating columns of trans-face-shared centred Hf9 cuboids. The columns form puckered slabs which are interconnected by homo- and heteronuclear bonds. Tellurium atoms are one-sidedly coordinated by six hafnium atoms. The coordination configurations about the two distinct tellurium atoms represent Hf6Te hypho-fragments of a tri-capped trigonal prismatic Hf9Te closo-cluster. Characteristic features of four other M2Q structure types are elucidated. The valence electron concentration available for metal-metal bonding together with the cohesive energy of the respective metal are found to control the formation of the various M2Q metal partial structures.
Zr stabilized Ti5Te4-type hafnium telluride
He, Meng,Simon, Arndt,Duppel, Viola
, p. 284 - 288 (2005)
A new Ti5Te4-type compound, Zr stabilized hafnium telluride was discovered and characterized with electron crystallography. Microanalyses and preparative work show that Zr stabilizes Ti5Te 4-type hafnium telluride and destabilizes the competing phase, Hf3Te2.
Solid-state tellurium-125 nuclear magnetic resonance studies of transition-metal ditellurides
Orion, Isabelle,Rocha, Joao,Jobic, Stephane,Abadie, Virginie,Brec, Raymond,Fernandez, Christian,Amoureux, Jean-Paul
, p. 3741 - 3748 (2007/10/03)
Solid-state 125Te NMR studies of inorganic compounds containing tellurium in oxidations states ranging from -II to VI have been made. The chemical shift tensors of Te(OH)6, TeCl4, TeO2 and elemental tellurium ha
Thermal Decomposition and Oxidation of HfTe5 Single Crystals
Saibene, S.,Butz, T.,Lerf, A.
, p. 1359 - 1362 (2007/10/02)
We report on time differential perturbed angular correlation measurements of the nuclear quadrupole interaction of (181)Hf(β(-))(181)Ta in HfTe5 single crystals during thermal decomposition and oxidation above room temperature. - HfTe5 decomposes under vacuum to HfTe3 + Te and finally to HfTe2 + Te at temperatures between 740-830 K and 820-860 K, respectively.Upon subsequent annealing at about 730 K both products recrystallize to HfTe5. - In air HfTe5 reacts at mild temperatures (380 K) and is completely transformed to a cream-coloured product after 220 h.Above 730 K this product reacts to HfTe3O8, which is stable up to 1050 K.At higher temperatures this material decomposes irreversibly to HfO2. - Key words: Phase Transitions / Solid State Reactions / Spectroscopy, Nuclear Quadrupole Resonance
Hf(SexTe1-x)2: Deviation from Végard's law in mixed systems
Hodul,Sienko
, p. 3655 - 3659 (2008/10/08)
Polycrystalline Hf(SexTe1-x)2 has been prepared by iodine mineralization from the elements at 800°C. Homogeneous solid solutions result over the range 0 a and c parameters, determined by using the Debye-Scherrer method, were found to vary linearly and parabolically, respectively, with composition. The non-Ve?gard behavior is ascribed to packing mismatches in the layers and is compared to behavior in other mixed transition-metal dichalcogenides. A brief comparison to pyrite systems is presented, and some general aspects of mixed materials are discussed.
