3911-49-7Relevant academic research and scientific papers
A three-aryl alcohol compound and its synthesis method
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Paragraph 0034; 0035; 0036; 0037; 0042-0045, (2019/07/08)
The invention discloses a three-aryl alcohol compound and its synthetic method, relates to the field of organic synthesis. The method is in the aerobic environment in a non-protic solvent, such as the formula (I) will be a compound represented by the gene
Oxidation of nitrobenzylic carbanions with dimethyldioxirane. New synthesis of quinomethanes and nitrobenzylic carbinols. First examples of methylation of carbanions with dimethyldioxirane
Makosza,Adam,Zhao,Surowiec
, p. 5022 - 5026 (2007/10/03)
The reaction of nitrobenzylic carbanions with dimethyldioxirane (DMD) results in oxidation at the carbanion center or at the nitronate center to give nitrobenzylic carbinols or quinomethanes, respectively. Minor amounts of the methylation products are also formed. Both of these processes were observed for carbanions of (p-nitroaryl)diarylmethanes. The outcome of the oxidation process is very sensitive to the reaction conditions.
Electron Apportionment in Cleavage of Radical Anions. 1. Nitro-Substituted Benzyl Phenyl Ethers
Maslak, Przemyslaw,Guthrie, Robert D.
, p. 2628 - 2636 (2007/10/02)
The radical anions of 4-nitrobenzyl phenyl ethers undergo cleavage at least 10E4 times faster than the radical anions of corresponding 4-nitrophenyl benzyl ethers despite a perceived thermodynamic advantage for the latter set of reactions.It is suggested that this results reflects a kinetic advantage for cleavage reactions which take place with regioconservation of spin density.
