39149-86-5Relevant academic research and scientific papers
Trapping reactive metal-carbene complexes by a bis-pocket porphyrin: X-ray crystal structures of Ru=CHCO2et and trans-[Ru(CHR)(CO)] species and highly selective carbenoid transfer reaction
Deng, Qing-Hai,Chen, Jian,Huang, Jie-Sheng,Chui, Stephen Sin-Yin,Zhu, Nianyong,Li, Guang-Yu,Che, Chi-Ming
, p. 10707 - 10712 (2009)
What's in my pockets? By employing Suslick's bis-pocket porphyrin (ttppp), a reactive M=CHCO2Et complex and a trans-[M(CHR)(CO)] (M = Ru) complex have been structurally characterized by X-ray crystal analysis. The sterically encumbered ttppp ligand has a significant impact on both the diastereoselectivity and chemoselectivity in metalloporphyrin-catalyzed reactions of ethyl diazoacetate with conjugated aryl dienes.
Ruthenium-porphyrin-catalyzed carbenoid addition to allylic compounds: Application to [2,3]-sigmatropic rearrangements of ylides
Simonneaux, Gérard,Galardon, Erwan,Paul-Roth, Christine,Gulea, Mihaela,Masson, Serge
, p. 360 - 363 (2007/10/03)
The catalytic effectiveness of ruthenium porphyrins for ylide generation in reactions of ethyl diazoacetate and diisopropyl diazomethylphosphonate with allylic amines, sulfides and iodides is described for the first time. These reactions result mainly in
