3917-24-6Relevant articles and documents
Catalytic asymmetric intramolecular hydroacylation with rhodium/phosphoramidite-alkene ligand complexes
Hoffman, Thomas J.,Carreira, Erick M.
supporting information; experimental part, p. 10670 - 10674 (2011/12/05)
Give me a P: An asymmetric intramolecular Rh-catalyzed hydroacylation reaction of pent-4-enals for the preparation of functionalized cyclopentanones in good yield and high enantioselectivity is described (see scheme, DCE=dichloroethane). This process uses rhodium complexes featuring novel modular phosphoramidite-alkene ligands and achiral phosphine coligands. Copyright