39185-14-3Relevant articles and documents
Perfluormethyl Element Ligands, XXIV; Organotin Compounds as Reagents, III. Cleavage Reactions of the Element-Element-Bond in Compounds of the Type RnE-ERm (R = CH3, CF3; E = P, As, S, Se, Te; n, m = 1, 2)
Dehnert, Peter,Grobe, Joseph,Van, Duc Le
, p. 48 - 54 (2007/10/02)
A systematic study of the cleavage of element-element bonds in compounds of the type RnE-ERm (R = CH3, CF3; E = P, As, S, Se, Te; n, m = 1, 2) by the group IV A element hydrides Me3M'H (M' = Si, Ge, Sn; Me = CH3) has been carried out.To evaluate the reaction pathway, for a number of compounds the attack of H2O, CH3OH, HBr and HI has been investigated.Possible reaction intermediates have been synthesized by independent routes and tested under comparable conditions. - Keywords: Organoelement-Element Compounds, Perfluoromethyl Derivatives, NMR Spectra
