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(11BR, 11'BR)-4,4'-(OXYDI-2,1-PHENYLENE& is a diphosphonite ligand that has been utilized in various chemical reactions due to its unique properties. It is characterized by its ability to form stable complexes with metals, which makes it a valuable component in catalysis.

391860-55-2

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391860-55-2 Usage

Uses

Used in Chemical Synthesis:
(11BR, 11'BR)-4,4'-(OXYDI-2,1-PHENYLENE& is used as a ligand in chemical synthesis for its ability to facilitate asymmetric catalysis. This enhances the selectivity and efficiency of the reactions, leading to the production of desired enantiomers with high purity.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, (11BR, 11'BR)-4,4'-(OXYDI-2,1-PHENYLENE& is used as a catalyst in the synthesis of complex molecules, such as those found in certain drugs. Its ability to promote asymmetric reactions allows for the production of specific drug enantiomers with desired biological activities, improving the effectiveness and safety of the final product.
Used in Asymmetric Rh-Catalyzed Conjugate Addition Reactions:
(11BR, 11'BR)-4,4'-(OXYDI-2,1-PHENYLENE& is used as a ligand for asymmetric Rh-catalyzed conjugate addition reactions of arylboronic acids to enones. This application takes advantage of the ligand's ability to induce selectivity in the reaction, resulting in the formation of chiral products with high enantiomeric purity.
Used in Asymmetric Hydrogenation Reactions:
In asymmetric hydrogenation reactions of β-keto esters, (11BR, 11'BR)-4,4'-(OXYDI-2,1-PHENYLENE& is employed as a ligand to achieve high levels of enantioselectivity. This is crucial for the production of optically active compounds that are often required in the pharmaceutical and agrochemical industries.
Overall, (11BR, 11'BR)-4,4'-(OXYDI-2,1-PHENYLENE& is a versatile diphosphonite ligand with a wide range of applications in chemical synthesis, pharmaceuticals, and catalysis, particularly in asymmetric reactions. Its ability to enhance selectivity and improve the efficiency of complex chemical transformations makes it a valuable tool in the development of new drugs and advanced materials.

Check Digit Verification of cas no

The CAS Registry Mumber 391860-55-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 3,9,1,8,6 and 0 respectively; the second part has 2 digits, 5 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 391860-55:
(8*3)+(7*9)+(6*1)+(5*8)+(4*6)+(3*0)+(2*5)+(1*5)=172
172 % 10 = 2
So 391860-55-2 is a valid CAS Registry Number.

391860-55-2 Well-known Company Product Price

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  • Aldrich

  • (682993)  (11bR,11′bR)-4,4′-(Oxydi-2,1-phenylene)bis-dinaphtho[2,1-d:,1′,2′-f][1,3,2]dioxaphosphepin  

  • 391860-55-2

  • 682993-100MG

  • 837.72CNY

  • Detail
  • Aldrich

  • (682993)  (11bR,11′bR)-4,4′-(Oxydi-2,1-phenylene)bis-dinaphtho[2,1-d:,1′,2′-f][1,3,2]dioxaphosphepin  

  • 391860-55-2

  • 682993-500MG

  • 3,164.85CNY

  • Detail

391860-55-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name R, R-Reetz D-Diphosphonite

1.2 Other means of identification

Product number -
Other names (11bS,11 inverted exclamation markabS)-4,4 inverted exclamation marka-(Oxydi-2,1-phenylene)bis-dinaphtho[2,1-d: 1 inverted exclamation marka,2 inverted exclamation marka-f][1,3,2]dioxaphosphepin

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:391860-55-2 SDS

391860-55-2Upstream product

391860-55-2Downstream Products

391860-55-2Relevant academic research and scientific papers

BINOL-based diphosphonites as ligands in the asymmetric Rh-catalyzed conjugate addition of arylboronic acids

Reetz, Manfred T.,Moulin, Dominique,Gosberg, Andreas

, p. 4083 - 4085 (2001)

matrix presented BINOL-based diphosphonites having achiral backbones are useful ligands in the Rh-catalyzed conjugate addition of arylboronic acids to α,β-unsaturated carbonyl compounds. The nature of the achiral backbone determines the direction and degr

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