391869-91-3

Upstream product

• 1517-82-4 (1R,2S,5R,SS)-(-)-menthyl p-toluenesulfinate 
• 26939-18-4 2,4,4,6-tetramethyl-5,6-dihydro-4H-1,3-oxazine 
• 391869-90-2 4,4,6-trimethyl-2-(toluene-4-sulfinylmethyl)-5,6-dihydro-4H-[1,3]oxazine 

Downstream Products

• 190279-13-1 (1R,S_R)-N-(p-methoxybenzyl)-1-(p-tolylsulfinylmethyl)-1,2,3,4-tetrahydro-9H-pyrido[3,4-b]indole 
• 190279-18-6 (1S,S_R)-N-(p-methoxybenzyl)-1-(p-tolylsulfinylmethyl)-1,2,3,4-tetrahydro-9H-pyrido[3,4-b]indole 
• 391869-93-5 (cis,S_R)-methyl-1-(p-tolylsulfinylmethyl)-1,2,3,4-tetrahydro-9H-pyrido[3,4-b]indole-3-carboxylate 
• 391869-94-6 (trans,S_R)-methyl-1-(p-tolylsulfinylmethyl)-1,2,3,4-tetrahydro-9H-pyrido[3,4-b]indole-3-carboxylate 
• 391869-95-7 (cis,S_R)-isopropyl-1-(p-tolylsulfinylmethyl)-1,2,3,4-tetrahydro-9H-pyrido[3,4-b]indole-3-carboxylate 
• 391869-96-8 (trans,S_R)-isopropyl-1-(p-tolylsulfinylmethyl)-1,2,3,4-tetrahydro-9H-pyrido[3,4-b]indole-3-carboxylate 

Relevant academic research and scientific papers

2-(Arylsulfinylmethyl)oxazinanes: Chiral carbonyl equivalents. Application to the asymmetric synthesis of 1,2,3,4-tetrahydro-β-carbolines

2-(p-Tolylsulfinylmethyl)oxazinane, a chiral carbonyl equivalent, has been synthesised and used for the diastereoselective synthesis of tetrahydro-β-carbolines including intermediates of yohimbine and herman alkaloids. A fair degree of diastereoselectivit

2-Arylsulfinylmethyl oxazines: Chiral carbonyl equivalents

A single pot acid catalysed condensation reaction of 2-arylsulfinylmethyloxazinane - a chiral carbonyl equivalent (derived from the title oxazine by BH4- reduction) with tryptamine and tryptophan esters, furnishes tetrahydro-β-carbol