39199-12-7

Usage

InChI:InChI=1/C7H14OS/c1-7(2,3)6(8)5-9-4/h5H2,1-4H3

Upstream product

• 75-97-8 3,3-dimethyl-butan-2-one 
• 5469-26-1 1-Bromopinacolon 
• 5188-07-8 sodium thiomethoxide 
• 88977-75-7 1-mercapto-3,3-dimethyl-butan-2-one 
• 77-78-1 dimethyl sulfate 

Downstream Products

• 75-97-8 3,3-dimethyl-butan-2-one 
• 21072-57-1 1,2,3,4-tetraphenyl-1,4-butane dione 
• 10516-92-4 1,2,3,4-tetraphenyl-1,4-butanedione 
• 39195-82-9 3,3-dimethyl-1-methylsulfanyl-butan-2-one oxime 
• 95151-34-1 Toluene-4-sulfonate(2-acetoxy-3,3-dimethyl-butyl)-dimethyl-sulfonium; 
• 95151-30-7 2-hydroxy-3,3-dimethylbutyl dimethyl sulphonium p-toluenesulphonate 

Relevant academic research and scientific papers

Rh/DuanPhos-Catalyzed Asymmetric Hydrogenation of β-Acetylamino Vinylsulfides: An Approach to Chiral β-Acetylamino Sulfides

Rh/DuanPhos-catalyzed asymmetric hydrogenation of challenging β-acetylamino vinylsulfides has been developed, affording chiral β-acetylamino sulfides with high yields and excellent ee's (up to 99% ee). This novel methodology provides an efficient and concise synthetic route to chiral β-acetylamino sulfides. The potential utility of this protocol in the synthesis of Apremilast has also been disclosed.

STEREOCHEMISTRY OF ORGANIC SULPHUR COMPOUNDS. PART 14 . SYNTHESIS AND CONFORMATION ANALYSIS OF 1-THIODERIVATIVES OF 3,3-DIMETHYL-2-BUTANOL AND ITS ACETATES.

The synthesis and conformational analysis of some thioderivatives tBu-CHX-CH2Y (X = OH and OAc; Y = SH, SMe, SO2Me and SMe2) are reported.The conformational equilibria have been established from 1H NMR data and high dilution ir studies.All the compounds exhibited almost monoconformational behaviour around the C(1)-C(2) bond, due to strong steric factors.The observed vicinal coupling constants were used to check the different parameterizations of Altona's equation for our compounds with sulphur in distinct oxidation states.The possible dihedral angle deformations were also evaluated.

Method of preparing ketoxime carbamates

A novel process of preparing ketoxime carbamate.

Ketoxime carbamates

Carbamate derivatives of ketoximes are useful in combatting pests such as insects, mites, and nematodes.

Ketoxime carbamates

Carbamate derivatives of ketoximes are useful in combatting pests such as insects, mites, and nematodes.