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ADDITION OF 1-IODO-1,2-DIFLUORO-1,2,2-TRICHLOROETHANE AND 1-IODO-1,2,2-TRIFLUORO-1,2-DICHLOROETHANE TO TRIFLUOROCHLOROETHENE AND 1,2-DIFLUOROCHLOROETHENE
Kremlev, M. M.,Cherednichenko, P. G.,Moklyachuk, L. I.,Yagupol'skii, L. M.
, p. 2316 - 2320 (2007/10/02)
It was shown that the addition of 1-iodo-1,2-difluoro-1,2,2-trichloroethane to trifluorochloroethene and also the addition of 1-iodo-1,2-difluoro-1,2,2-trichloroethane and 1-iodo-1,2,2-trifluoro-1,2-dichloroethane to 1,2-difluorochloroethene lead to the formation of mixtures of telomers. 1-Chloro- and 1,4-dichloroperfluorobutadiene and 1,6-dichloroperfluorohexatriene were obtained from polyhalogenobutanes and hexanes by successive dehydrohalogenation, chlorination, and dechlorination.It was shown that 1,1,2,3,4-pentafluoropentachlorobutane and 1,1,2,3,4,5,6-heptafluoroheptachlorohexane form α-aryl-ω-chloroperfluoropolyenes in reaction with arylmagnesium bromides.
