39212-16-3Relevant academic research and scientific papers
Direct Reduction of Allylic Alcohols Using Isopropanol as Reductant
Sai, Masahiro
supporting information, p. 3482 - 3487 (2018/09/14)
The lithium cation-catalyzed direct reduction of allylic alcohols to alkenes using isopropanol as a hydride donor was developed. The hydride transfer of the in situ-generated lithium isopropoxide to an allylic cation is the key process in this transformation. The reaction generates only water and acetone as byproducts, which highlights the synthetic utility of this method. (Figure presented.).
Electrophilic addition of allylic carbocations to 2-cyclopropylidene-2- arylethanols: A strategy to 3-oxabicyclo[3.2.0]heptanes
Meng, Bo,Huang, Xian,Wu, Luling
, p. 2637 - 2650 (2013/10/21)
We have developed an electrophilic addition of allylic carbocations to 2-cyclopropylidene-2-arylethanols constructing carbon-carbon bonds with excellent regio- and stereoselectivities. The reaction affords 3-oxabicyclo[3.2.0]heptanes in moderate to good y
Electronic effects in the regioselectivity of nucleophilic attacks on cationic 1,3-diaryl-π-allylpalladium complexes
Prat,Ribas,Moreno-Manas
, p. 1695 - 1706 (2007/10/02)
Nucleophilic attacks on π-allylpalladium complexes derived from O2N-Ph-(CH-CH-CH)-Ph-X systems (X = 4-OMe and 4-Cl) occur preferentially at the allylic terminus remote from the electron-withdrawing group (NO2).
