3922-17-6Relevant academic research and scientific papers
Synthesis of Carbamoyl Fluorides via a Selective Fluorinative Beckmann Fragmentation
Lim, Hee Nam,Song, Jin Woo
supporting information, p. 5394 - 5399 (2021/07/26)
A fluorinative Beckmann fragmentation of α-oximinoamides was devised to provide synthetically useful carbamoyl fluorides. High selectivity for fragmentation over a potentially competing Beckmann rearrangement was observed. This protocol has a distinct mechanism and thus a different substrate scope compared with other synthetic methods. α-Oximinoamides derived from the readily available secondary amines, lactams, or isatins were converted into structurally diverse carbamoyl fluorides.
Glycosides of hydroxylamine derivatives: I. Phase transfer synthesis and the study of the influence of glucosaminides of isatine 3-oximes on bacterial luminescence
Kuryanov,Chupakhina,Shapovalova,Katsev,Chirva
body text, p. 231 - 239 (2012/05/20)
Easily deprotoned hydroxyl groups of isatine 3-oximes were glycosylated in high yields by α-D-glucosaminyl chloride peracetate in the solid potassium carbonate-acetonitrile phase transfer system. It was found that catalytic amounts of 15-crown-5 supported
Microwave-assisted three-component synthesis of some novel 1-alkyl-1H-indole-2,3-dione 3-(o-alkyloxime) derivatives as potential chemotherapeutic agents
Soltani Rad, Mohammad Navid,Khalafi-Nezhad, Ali,Babamohammadi, Somayeh,Behrouz, Somayeh
experimental part, p. 2454 - 2466 (2011/02/18)
A convenient and efficient method for a one-pot conversion of N-alkylisatins to N-alkylisatin O-alkyloximes 7a-7n as potential chemotherapeutic agents is described (Scheme) (isatin=1H-indole-2,3-dione). In this method, the microwave-assisted three-compone
