39220-74-1Relevant academic research and scientific papers
Dual Ligand-Enabled Nondirected C-H Cyanation of Arenes
Chen, Hao,Mondal, Arup,Wedi, Philipp,Van Gemmeren, Manuel
, p. 1979 - 1984 (2019/02/19)
Aromatic nitriles are key structural units in organic chemistry and, therefore, highly attractive targets for C-H activation. Herein, the development of an arene-limited, nondirected C-H cyanation based on the use of two cooperatively acting commercially available ligands is reported. The reaction enables the cyanation of arenes by C-H activation in the absence of directing groups and is therefore complementary to established approaches.
Cyano or Acyl Group Migration by Consecutive Homolytic Addition and β-Fission
Beckwith, Athelstan L. J.,O'Shea, Dennis M.,Gerba, Sendaba,Westwood, Steven W.
, p. 666 - 667 (2007/10/02)
Suitably constituted aryl and alkyl radicals readily rearrange by 1,2- or 1,4-acyl or cyano migration.
