39248-94-7

Basic information

• Product Name: S-(4-fluorophenyl) 4-methylbenzothioate
• Synonyms: S-(4-fluorophenyl) 4-methylbenzothioate
• CAS NO: 39248-94-7
• Molecular Weight: 246.305
• Mol File: 39248-94-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: S-(4-fluorophenyl) 4-methylbenzothioate(CAS DataBase Reference)
• NIST Chemistry Reference: S-(4-fluorophenyl) 4-methylbenzothioate(39248-94-7)
• EPA Substance Registry System: S-(4-fluorophenyl) 4-methylbenzothioate(39248-94-7)

Safety Data

• Hazardous Substances Data: 39248-94-7(Hazardous Substances Data)

Upstream product

• 371-42-6 4-Fluorothiophenol 
• 624-31-7 4-tolyl iodide 
• 874-60-2 4-methyl-benzoyl chloride 

Downstream Products

• 1173164-11-8 C₂₂H₂₅FOS 
• 1173163-79-5 C₂₂H₂₅FOS 

Relevant articles and documents

Oxalic Acid Monothioester for Palladium-Catalyzed Decarboxylative Thiocarbonylation and Hydrothiocarbonylation

Oxalic acid monothioester (OAM), an easily accessible and storable reagent, was reported herein as a thioester synthetic equivalent for palladium-catalyzed decarboxylative thiocarbonylation of organohalides and hydrothiocarbonylation of unsaturated carbon-carbon bonds at room temperature with high chemo- and regioselectivity. The reaction is applicable to the synthesis of cysteine-derived thioesters, thus allowing chemical modification of cysteine-containing peptides. Decarboxylation of OAM proceeds through oxidative addition of Pd(0) to the acyl-S bond, which accounts for the very mild reaction conditions.