392664-15-2

Upstream product

• 824-94-2 p-methoxybenzyl chloride 
• 14133-63-2 methyl 2,3-O-isopropylidene-α-L-rhamnoside 
• 2746-25-0 p-Methoxybenzyl bromide 

Downstream Products

• 392664-05-0 methyl 4-O-(4-methoxybenzyl)-α-L-rhamnopyranoside 
• 847158-99-0 methyl 3-O-acetyl-4-O-(4-methoxybenzyl)-α-L-rhamnopyranoside 

Relevant academic research and scientific papers

Induction of a preferred sense of twist in flexible diphenyls by carbohydrate scaffolds. Synthesis of two "naked" ellagitannin analogous

The synthesis of "naked" ellagitannin analogues 1 and 2, having a preferred sense of twist of the diphenyl moiety, with a rhamnose and a glucose template, is reported. A clear induction in the chirality of the diphenyl moiety, mediated through a 10-membered ring via ester linkages, was observed. The chiral scaffold of glucose (diequatorial 2,3-hydroxyl groups) exerts a remarkable stronger atropdiastereoselective effect onto the diphenoyl group than the rhamnose ring (axial-equatorial 2,3-hydroxyl groups), according to the Schmidt-Haslam hypothesis.

Synthesis of a 2,3,4-triglycosylated rhamnoside fragment of rhamnogalacturonan-II side chain a using a late stage oxidation approach

(Chemical Equation Presented) Pectic polysaccharide RG-II, a key component of plant primary cell walls, is known to exist as a dimer formed by means of borate diester cross-links between apiosyl residues of one of its constituent side-chain oligosaccharid