3938-13-4Relevant articles and documents
1,3-Halogen shift of 2-halogeno-4,5-dimethylphenols following oxidation with Fremy's salt
Jacobs, A. W. C. M.,Maat, L.
, p. 183 - 185 (2007/10/02)
Oxidation of 2-bromo-6-deuterio-4,5-dimethylphenol with Fremy's salt, followed by in situ reduction, yielded mainly 3-bromo-4,5-dimethylpyrocatechol, which affords evidence for a 1,3-bromine shift during the oxidation.The same treatment of 2-chloro-4,5-di