3945-25-3

Upstream product

• 533-67-5 2-Deoxy-D-ribose 
• 62-53-3 aniline 
• 93857-40-0 sodium 3-deoxy-D-mannonate 
• 5284-18-4 D-threo-2-deoxy-pentose 
• 533-67-5 2-deoxy-D-ribose 
• 79576-62-8 5-hydroxy-pent-3-ynal-dimethylacetal 
• 79576-67-3 5,5-dimethoxy-pent-2c-en-1-ol 
• 22900-10-3 2-deoxy-D-ribose 
• 190186-35-7 Acetic acid (E)-(1R,2S)-2-acetoxy-1-acetoxymethyl-4-phenylazo-but-3-enyl ester 
• 190186-36-8 (2R,3S)-5-(Phenyl-hydrazono)-pentane-1,2,3-triol 

Downstream Products

• 108514-99-4 2-anilino-D-arabino-2,3-dideoxy-hexononitrile 
• 108514-99-4 2-anilino-D-ribo-2,3-dideoxy-hexononitrile 
• 119040-45-8 bis-O-(toluene-4-sulfonyl)-D-ribo-2,5-anhydro-3-deoxy-hexonic acid dimethylamide 
• 79827-70-6 1-(N,N-dimethylcarboxamido)-2-deoxy-5-O-tosyl-β-D-erythropentofuranose 
• 108846-30-6 2-anilino-D-ribo-2,3-dideoxy-hexonic acid-4-lactone; hydrochloride 

Relevant academic research and scientific papers

Production of aldoses

An aldose having n-1 carbon atoms is produced from an aldonic acid having n carbon atoms using hypochlorous acid or a hypochlorite in a high yield at low cost with safety, by treating the reaction mixture with a compound having reactivity with the hypochlorous acid or hypochlorite higher than that with the produced aldose.

Preparation of 2-deoxyaldoses from aldose phenylhydrazones

Acetylation of D-mannose phenylhydrazone gives acetylated D-arabino-1-phenyl-azo-1-(E)-hexene. Subsequent reduction with sodium borohydride produces 2-deoxy-D-arabino-hexose phenylhydrazone which, on hydrolysis, gives 2-deoxy-D-arabino-hexose. By a similar procedure 2-deoxy-D-lyxo-hexose, 2,6-dideoxy-L-arabino-hexose, and 2-deoxy-D-erythropentose can be prepared from D-galactose, L-rhamnose, and D-arabinose, respectively.