39546-85-5Relevant academic research and scientific papers
Vinylic Organoboranes. 6. A General Synthesis of (E)-Disubstituted Alkenes or Ketones via the (E)-(1-Substituted-1-alkenyl)boronic Esters
Brown, Herbert C.,Basavaiah, D.,Kulkarni, Surendra U.,Lee, Hsiupu D.,Negishi, Ei-ichi,Katz, Jean-Jacques
, p. 5270 - 5276 (2007/10/02)
Development of a general stereospecific synthesis of (E)-disubstituted alkenes utilizing a variety of hydroborating agents such as monohaloborane, thexylborane, thexylchloroborane, and dibromoborane is discussed.Hydroboration of 1-halo-1-alkynes with dial
