395642-62-3

Upstream product

• 7486-35-3 tri-n-butyl(vinyl)tin 
• 395642-64-5 2-Bromo-3-hydroxycyclohex-1-enyl triflate 
• 395642-61-2 2-bromo-3-ethenyl-2-cyclohexen-1-one 
• 85493-96-5 2-bromo-3-methoxy-2-cyclohexenone 
• 1619228-49-7 2-bromo-3-(prop-2-yn-1-yloxy)-1-vinylcyclohex-1-ene 
• 395642-60-1 2-bromo-3-oxocyclohex-1-en-1-yl trifluoromethanesulfonate 
• 60060-44-8 2-bromocyclohexane-1,3-dienone 

Downstream Products

• 1619228-49-7 2-bromo-3-(prop-2-yn-1-yloxy)-1-vinylcyclohex-1-ene 

Relevant academic research and scientific papers

Halogen effect on tandem [4+2] cycloaddition/aromatization sequence of allenyl 2-halo-3-vinylcyclohex-2-enyl ether

Steric and enthalpic effects of substituents on diene moieties play a crucial role in intramolecular cycloaddition reactions. Allenyl 2-halogenated-3-vinylcyclohex-2-enyl ethers underwent a tandem [4+2] cycloaddition/aromatization reaction to afford the corresponding tetrahydro-3H-naphtho[1,8-bc]furan compound in high yield.

A one-pot sequence of Stille and Heck couplings: Synthesis of various 1,3,5-hexatrienes and their subsequent 6π-electrocyclizations

Palladium-catalyzed crosscoupling reactions of 2-bromocyclohex1-enyl triflates 7 and 11 with a variety of alkenylstannanes occurred chemoselectively at the site of the triflate leaving group to give bromobutadienes which readily underwent Heck reactions w