395642-65-6

Basic information

• Product Name: Methanesulfonic acid, trifluoro-, 2-bromo-3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-1-cyclohexen-1-yl ester
• CAS NO: 395642-65-6
• Molecular Formula: C13H22BrF3O4SSi
• Molecular Weight: 439.366
• Mol File: 395642-65-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Methanesulfonic acid, trifluoro-, 2-bromo-3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-1-cyclohexen-1-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Methanesulfonic acid, trifluoro-, 2-bromo-3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-1-cyclohexen-1-yl ester(395642-65-6)
• EPA Substance Registry System: Methanesulfonic acid, trifluoro-, 2-bromo-3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-1-cyclohexen-1-yl ester(395642-65-6)

Safety Data

• Hazardous Substances Data: 395642-65-6(Hazardous Substances Data)

Upstream product

• 395642-60-1 2-bromo-3-oxocyclohex-1-en-1-yl trifluoromethanesulfonate 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 395642-64-5 2-Bromo-3-hydroxycyclohex-1-enyl triflate 
• 60060-44-8 2-bromocyclohexane-1,3-dienone 

Relevant articles and documents

A one-pot sequence of Stille and Heck couplings: Synthesis of various 1,3,5-hexatrienes and their subsequent 6π-electrocyclizations

Palladium-catalyzed crosscoupling reactions of 2-bromocyclohex1-enyl triflates 7 and 11 with a variety of alkenylstannanes occurred chemoselectively at the site of the triflate leaving group to give bromobutadienes which readily underwent Heck reactions w