396131-82-1 Usage
Uses
3-(Cyanomethyl)benzeneboronic acid pinacol ester is used as pharmaceutical intermediate.
Check Digit Verification of cas no
The CAS Registry Mumber 396131-82-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 3,9,6,1,3 and 1 respectively; the second part has 2 digits, 8 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 396131-82:
(8*3)+(7*9)+(6*6)+(5*1)+(4*3)+(3*1)+(2*8)+(1*2)=161
161 % 10 = 1
So 396131-82-1 is a valid CAS Registry Number.
InChI:InChI=1/C14H18BNO2/c1-13(2)14(3,4)18-15(17-13)12-7-5-6-11(10-12)8-9-16/h5-7,10H,8H2,1-4H3
396131-82-1Relevant articles and documents
Radical Metal-Free Borylation of Aryl Iodides
Pinet, Sandra,Liautard, Virginie,Debiais, Mégane,Pucheault, Mathieu
, p. 4759 - 4768 (2017/10/03)
A simple metal-free borylation of aryl iodides mediated by a fluoride sp 2 -sp 3 diboron adduct is described. The reaction conditions are compatible with various functional groups. Electronic effects of substituents do not affect the borylation while steric hindrance does. The reaction proceeds via a radical mechanism in which pyridine serves to stabilize the boryl radicals, generated in situ.
