39664-88-5

Upstream product

• 14149-03-2 (1R,2S)-(-)-2-Amino-1,2-diphenyl-1-ethanol hydrochloride 
• 77287-34-4 formamide 
• 23190-16-1 (1R,2S)-2-Amino-1,2-diphenylethanol 
• 109-94-4 formic acid ethyl ester 
• 301191-47-9 N-[(1S,2S)-2-hydroxy-1,2-diphenylethyl]formamide 
• 530-36-9 (1S,2S)-2-amino-1,2-diphenylethanol 
• 50-00-0 formaldehyd 
• 530-36-9 threo-1,2-diphenyl-2-aminoethan-1-ol 

Downstream Products

• 530-36-9 (1S,2S)-2-amino-1,2-diphenylethanol 
• 550-58-3 (1S,2S)-1,2-diphenyl-2-(N-methyl)aminoethanol 
• 301191-47-9 N-[(1S,2S)-2-hydroxy-1,2-diphenylethyl]formamide 
• 1380325-25-6 N-[(1S,2S)-2-hydroxy-1,2-diphenylethyl]-N-methylbutyramide 
• 1380325-26-7 N-[(1S,2S)-2-hydroxy-1,2-diphenylethyl]-N-methylmethacrylamide 
• 1380325-27-8 N-[(1S,2S)-2-hydroxy-1,2-diphenylethyl]-N-methyl-3-phenylpropanamide 
• 1380325-28-9 N-[(1S,2S)-2-hydroxy-1,2-diphenylethyl]-N-methylhexanamide 
• 1380325-29-0 N-[(1S,2S)-2-hydroxy-1,2-diphenylethyl]-N-methyl-2-methylenebutanamide 
• 1380325-30-3 N-[(1S,2S)-2-hydroxy-1,2-diphenylethyl]-N-methyl-2-methyleneheptanamide 
• 1380325-31-4 (R)-N-[(1S,2S)-2-hydroxy-1,2-diphenylethyl]-N,2-dimethyl-3-phenylpropanamide 
• 1380325-33-6 CF₃O₃S^(1-)*C₂₅H₂₆NO⁽¹⁺⁾ 
• 1380325-34-7 (R)-N-[(1S,2S)-2-hydroxy-1,2-diphenylethyl]-N,2-dimethylhexanamide 
• 1380325-35-8 (R)-N-[(1S,2S)-2-hydroxy-1,2-diphenylethyl]-N,2-dimethylbutanamide 
• 1380325-36-9 (S)-N-[(1S,2S)-2-hydroxy-1,2-diphenylethyl]-N,2-dimethylbutanamide 

Relevant academic research and scientific papers

Aminophosphine phosphinites derived from chiral 1,2-diphenyl-2-aminoethanols: Synthesis and application in rhodium-catalyzed asymmetric hydrogenation of dehydroamino acid derivatives

A series of chiral aminophosphine phosphinites DPAMPPs was synthesized from optically active 1,2-diphenyl-2-aminoethanols. The erythro-DPAMPPs were found to serve as excellent ligands for rhodium-catalyzed asymmetric hydrogenation of dehydroamino acid derivatives. For an array of dehydroamino acid precursors, remarkably high enantioselectivity (up to 98.4% e.e.) and reactivity (the ratio of substrate/catalyst up to 10000) were observed. Some factors controlling the enantioselectivity were examined and discussed. (C) 2000 Elsevier Science Ltd.

Pseudoephenamine: A practical chiral auxiliary for asymmetric synthesis

Unrestricted: Pseudoephenamine is introduced as a versatile chiral auxiliary and an alternative to pseudoephedrine in asymmetric synthesis. It is free from regulatory restrictions and leads to remarkable stereocontrol in alkylation reactions, especially in those that form quaternary carbon centers. Amides derived from pseudoephenamine exhibit a high propensity to be crystalline substances, and provide sharp, well-defined signals in NMR spectra. Copyright

Enzyme-Catalyzed Reactions, 8. - Stereoselective Synthesis of 2-Amino Alcohols from (R)- and (S)-Cyanohydrins

erythro-2-Amino alcohols (1R,2S)- and (1S,2R)-4 may be synthesized stereoselectively by addition of Grignard compounds to cyanohydrins (R)-, (S)-1 and their O-trimethylsilyl derivatives 3, respectively, followed by hydrogenation.The threo-2-amino alcohols (1S,2S)- and (1R,2R)-4 are easily accessible by inversion at C-1 of the (1R,2S) and (1S,2R) compounds.