39697-14-8

Upstream product

• 103-30-0 (E)-1,2-diphenyl-ethene 
• 12120-15-9 ethylenebis(triphenylphosphine)platinum⁽⁰⁾ 

Downstream Products

• 77543-73-8 3-phenylthiete 1,1-dioxidebis(triphenylphosphine)platinum⁽⁰⁾ 
• 77543-75-0 3-p-bromophenylthiete 1,1-dioxidebis(triphenylphosphine)platinum⁽⁰⁾ 
• 50701-22-9 {(C₆H₅)3P}2PtC(CF₂)HCF₃ 
• 25358-31-0 cis-chloro(phenylethynyl)bis(triphenylphosphine)platinum(II) 
• 25358-31-0 trans-chloro(phenylacetylenyl)bis(triphenylphosphine)platinum 
• 69350-05-6 trans-iodo(phenylethynyl)bis(triphenylphosphine)platinum(II) 
• 69350-04-5 cis-bromo(phenylethynyl)bis(triphenylphosphine)platinum(II) 
• 69350-04-5 trans-bromo(phenylethynyl)bis(triphenylphosphine)platinum(II) 
• 69289-56-1 cis-iodo(phenylethynyl)bis(triphenylphosphine)platinum(II) 
• 58355-00-3 cis-[PtCl(CF₂COCF₂Cl)(PPh₃)2] 
• 65852-79-1 cis-[PtCl(CF₂COCF₃)(PPh₃)2] 
• 160491-54-3 Pt(OOC(CH₃)(CH₂C(O)NH(C₆H₅))O)(P(C₆H₅)3)2 
• 105302-65-6 Pt(η(2)-CH2C(O)CH2)(PPh3)2 
• 105302-65-6 {Pt(η3-CH2C(O)CH2)(PPh3)2} 

Relevant academic research and scientific papers

Synthesis and characterization of platinum(0) alkene complexes; X-ray crystal structure determinations on [Pt(trans-PhCH=CHCHO)(PPh3)2] and [Pt(trans-PhCH=CHCOMe)(PPh3)2]

Reaction of [Pt(C2H4)(PPh3)2] with a range of alkenes gave the complexes [Pt(alkene)(PPh3)2]. Complexes of alkenes bearing electron-withdrawing ligands were, predictably, more stable than those of electron-rich alkenes. The complexes were characterized by multinuclear (1H, 13C, 31P and 195Pt) NMR spectroscopy and the structures of the derivatives of trans-PhCH=CHCHO and trans-PhCH=CHCOMe were established by X-ray diffraction studies. The complexes reacted with PCy3 to give [Pt(alkene)(PCy3)(PPh3)], usually as a mixture of regioisomers. Copyright