39701-87-6

Basic information

• Product Name: methyl (2Z,4E)-5-((1S,4S)-1,4-dihydroxy-2,6,6-trimethylcyclohex-2-en-1-yl)-3-methylpenta-2,4-dienoic acid
• Synonyms: methyl (2Z,4E)-5-((1S,4S)-1,4-dihydroxy-2,6,6-trimethylcyclohex-2-en-1-yl)-3-methylpenta-2,4-dienoic acid
• CAS NO: 39701-87-6
• Molecular Weight: 280.364
• Mol File: 39701-87-6.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: methyl (2Z,4E)-5-((1S,4S)-1,4-dihydroxy-2,6,6-trimethylcyclohex-2-en-1-yl)-3-methylpenta-2,4-dienoic acid(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (2Z,4E)-5-((1S,4S)-1,4-dihydroxy-2,6,6-trimethylcyclohex-2-en-1-yl)-3-methylpenta-2,4-dienoic acid(39701-87-6)
• EPA Substance Registry System: methyl (2Z,4E)-5-((1S,4S)-1,4-dihydroxy-2,6,6-trimethylcyclohex-2-en-1-yl)-3-methylpenta-2,4-dienoic acid(39701-87-6)

Safety Data

• Hazardous Substances Data: 39701-87-6(Hazardous Substances Data)

Upstream product

• 118711-66-3 C₁₆H₂₄O₃⁽¹⁸⁾O 
• 21293-29-8 (2Z,4E)-5-(1-hydroxy-2,6,6-trimethyl-4-oxo-2-cyclohexen-1-yl)-3-methyl-2,4-pentadienoic acid 
• 6901-96-8 abscisic acid methylester 
• 186581-53-3 diazomethane 
• 20110-02-5 (+/-)-abscisic acid cis-1',4'-diol 
• 122346-87-6 C₁₈H₂₆O₅ 
• 79434-13-2 (+)-(S)-5-(1'-Hydroxy-2',6',6'-trimethyl-4'-oxocyclohex-2'-enyl)-3-methylpenta-2,4-diensaeure-methylester 
• 6901-90-2 (1'S,2E,4E)-5-(1'-Hydroxy-2',6',6'-trimethyl-4'-oxo-2'-cyclohexenyl)-3-methyl-2,4-pentadiensaeure-methylester 
• 2228-72-0 Abscisic acid 
• 851040-82-9 (+)-(2Z,4E)-methyl trans-1',4'-dihydroxy-γ-ionylideneacetate 
• 20109-89-1 (2Z,4E)-methyl 5-(1',4'-dihydroxy-2',6',6'-trimethyl-2'-cyclohexen-1'-yl)-3-methylpenta-2,4-dienoate 
• 6901-90-2 (S)-methyl abscisate 

Downstream Products

• 19598-75-5 5-<1-Hydroxy-6.6-dimethyl-2-methylen-Δ³-cyclohexenyl-(1)>-3-methyl-pentadien-(2trans.4trans)-saeuremethylester 
• 6901-90-2 (S)-methyl abscisate 
• 14398-53-9 (R)-(-)-abscisic acid 
• 19598-74-4 5-<1-Hydroxy-6.6-dimethyl-2-methylen-Δ³-cyclohexenyl-(1)>-3-methyl-pentadien-(2cis.4trans)-saeuremethylester 
• 85718-96-3 (2Z,4E)-5-((1S,4S)-1,4-dihydroxy-2,6,6-trimethylcyclohex-2-en-1-yl)-3-methylpenta-2,4-dienoic acid 
• 130847-03-9 (3'RS,4'S)-5-(3',4'-Diacetoxy-2',6',6'-trimethylcyclohex-1'-enyl)-3-methylpenta-2,4-diensaeure-methylester 
• 130930-83-5 (3'S,4'S)-5-(3',4'-Dihydroxy-2',6',6'-trimethylcyclohex-1'-enyl)-3-methylpenta-2,4-diensaeure-methylester 
• 130847-04-0 (3'R,4'S)-5-(3',4'-Dihydroxy-2',6',6'-trimethylcyclohex-1'-enyl)-3-methylpenta-2,4-diensaeure-methylester 
• 2228-72-0 Abscisic acid 
• 118711-66-3 C₁₆H₂₄O₃⁽¹⁸⁾O 
• 130856-61-0 (+)-(1'S,4'S)-5-(4'-Acetoxy-1'-hydroxy-2',6',6'-trimethylcyclohex-2-enyl)-3-methylpenta-2',4'-diensaeure-methylester 
• 130856-62-1 (+)-(1'S,4'R)-5-(4'-Acetoxy-1'-hydroxy-2',6',6'-trimethylcyclohex-2-enyl)-3-methylpenta-2',4'-diensaeure-methylester 

Relevant articles and documents

THE 1',4'-TRANS-DIOL OF ABSCISIC ACID, A POSSIBLE PRECURSOR OF ABSCISIC ACID IN BOTRYTIS CINEREA

Key Word Index - Botrytis cinerea; Hyphomycetes; abscisic acid; biosynthesis; 1',4'-trans-diol of abscisic acid; 1',4'-dihydroxy-α-ionylideneacetic acid.The 1',4'-trans-diol of abscisic acid was isolated from cultures of Botrytis cinerea.The 2H-labelled d

Asymmetrical ligand binding by abscisic acid 8′-hydroxylase

Abscisic acid (ABA), a plant stress hormone, has a chiral center (C1′) in its molecule, yielding the enantiomers (1′S)-(+)-ABA and (1′R)-(-)-ABA during chemical synthesis. ABA 8′-hydroxylase (CYP707A), which is the major and key P450 enzyme in ABA catabol

Biosynthesis of Abscisic Acid by the Non-mevalonate Pathway in Plants, and by the Mevalonate Pathway in Fungi

The biosynthetic pathways to abscisic acid (ABA) were investigated by feeding [1-13C]-D-glucose to cuttings from young tulip tree shoots and to two ABA-producing phytopathogenic fungi. 13C-NMR spectra of the ABA samples isolated showed that the carbons at 1, 5, 6, 4′, 7′ and 9′ of ABA from the tulip tree were labeled with 13C, while the carbons at 2, 4, 6, 1′, 3′, 5′, 7′, 8′ and 9′ of ABA from the fungi were labeled with 13C.The former corresponds to C-1 and -5 of isopentenyl pyrophosphate, and the latter to C-2, -4 and -5 of isopentenyl pyrophosphate. This finding reveals that ABA was biosynthesized by the non-mevalonate pathway in the plant, and by the mevalonate pathway in the fungi. 13C-Labeled ss;-carotene from the tulip tree showed that the positions of the labeled carbons were the same as those of ABA, being consistent with the biosynthesis of ABA via carotenoids. Lipiferolide of the tulip tree was also biosynthesized by the non-mevalonate pathway.