39728-57-9Relevant academic research and scientific papers
KETONES AND METHOD FOR MANUFACTURING ANALOG THEREOF
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Paragraph 0081-0084, (2019/04/05)
PROBLEM TO BE SOLVED: To provide a technique for efficiently producing ketones by using cellulose after extracting chitin and chitosan extracted from the crustacean or sucrose from the beet in order to effectively using wastes, such as a crustacean or a beat to prepare a solid catalyst. SOLUTION: A method for manufacturing 1-phenyl-3-ketones and an analog (a compound 3) comprises using at least one kind selected from a group consisting of cellulose, chitin and chitosan as a carrier and reacting benzyl alcohols (a compound 1) with ketones (a compound 2) in the presence of a solid catalyst obtained by supporting a group 8-10 transition metal and a base. The following chemical formula 1 is shown. SELECTED DRAWING: None COPYRIGHT: (C)2019,JPOandINPIT
Simple Synthesis of Phytochemicals by Heterogeneous Pd- and Ir-Catalyzed Hydrogen-Borrowing C–C Bond Formation
Hori, Yoji,Suruga, Chiharu,Akabayashi, Yuta,Ishikawa, Tomoka,Saito, Marina,Myoda, Takao,Toeda, Kazuki,Maeda, Yuna,Yoshida, Yutaka
supporting information, p. 7295 - 7299 (2018/01/02)
Chitin-supported palladium and iridium catalysts (i.e., Pd/chitin, Ir/chitin) successfully promote the hydrogen borrowing C–C bond formation reaction to afford phytochemicals and aroma compounds in excellent yields.
