397330-67-5Relevant academic research and scientific papers
Synthesis of fluorinated triazole and isoxazole derivatives by electrochemical fluorination
Kuribayashi, Shunsuke,Shida, Naoki,Inagi, Shinsuke,Fuchigami, Toshio
, p. 5343 - 5349 (2016/08/04)
Partially fluorinated triazole derivatives were synthesized through anodic fluorination of alkynes having arylthio group and following Cu(I)-catalyzed azide-alkyne cycloaddition (CuAAC) with benzyl azide. The other route toward the fluorinated triazoles,
Electrolytic partial fluorination of organic compounds. Part 57: Regioselective anodic monofluorination of nitrogen-containing heterocyclic propargyl sulfides
Riyadh, Sayed M,Ishii, Hideki,Fuchigami, Toshio
, p. 8817 - 8821 (2007/10/03)
Anodic fluorination of various nitrogen-containing heterocyclic propargyl sulfides using Et4NF·nHF (n=3,4) or Et3N·3HF as a supporting electrolyte and fluoride ion source in dimethoxyethane provided the corresponding monofluorinated products in moderate yields. Fluorination took place selectively at the position α to the sulfur atom of the sulfides and the heterocyclic moieties were not fluorinated at all.
