39734-10-6Relevant academic research and scientific papers
FORMATION AND REACTIVITY OF PALLADIUM HYDRIDE COMPLEXES, + AND +, IN AQUEOUS TRIFLUOROACETIC ACID SOLUTIONS
Zudin, V. N.,Chinakov, V. D.,Nekipelov, V. M.,Likholobov, V. A.,Yermakov, Yu. I.
, p. 425 - 430 (1985)
Interaction of H2 with P2PdX2 complex (P=PPh3, X=CF3COO) in aqueous trifluoroacetic acid solution at 70 deg C in excess triphenylphosphine results in the formation of the palladium hydride complex +.The same complex is formed by protonat
Formation of anionic palladium(0) complexes ligated by the trifluoroacetate ion and their reactivity in oxidative addition
Amatore, Christian,Jutand, Anny,Lema?tre, Frédéric,Ricard, Jean Luc,Kozuch, Sebastian,Shaik, Sason
, p. 3728 - 3734 (2007/10/03)
As established previously for Pd(OAc)2, Pd0 complexes are formed in situ from Pd(OCOCF3)2 and n equiv. triarylphosphines (4-Z-C6H4)3P (Z = CF 3, F, Cl, H, CH3/su
