39741-81-6

Usage

Uses

Used in Organic Synthesis:
[(E)-but-2-enyl]-triphenyl-phosphanium is used as a versatile organophosphorus reagent for various organic synthesis reactions. Its unique reactivity and molecular structure make it a valuable component in this field.
Used in Catalysis:
[(E)-but-2-enyl]-triphenyl-phosphanium is also studied for its potential application in catalysis, where it can contribute to enhancing the efficiency and selectivity of chemical reactions.
Used as a Ligand in Transition Metal Complexes:
[(E)-but-2-enyl]-triphenyl-phosphanium is used as a ligand in the formation of transition metal complexes, which are essential in various chemical and industrial processes.
Used in Pharmaceutical Research:
Its potential applications extend to the pharmaceutical industry, where it can be utilized in the development of new drugs and therapeutic agents.
Used in Material Science Research:
[(E)-but-2-enyl]-triphenyl-phosphanium also holds promise in material science research, where its unique properties can be harnessed to create novel materials with specific characteristics.

Upstream product

• 106-95-6 allyl bromide 
• 603-35-0 triphenylphosphine 
• 4784-77-4 (E/Z)-crotyl bromide 
• 4784-77-4 (E)-1-Bromo-2-butene 

Downstream Products

• 1608-27-1 1-phenylpenta-1,3-diene 
• 1065271-68-2 (1'Z,3'E,2S,3R,4S)-3-(tert-butyldiphenylsilanyloxy)-2-(tert-butyldiphenylsilanyloxymethyl)-4-(penta-1',3'-dienyl)tetrahydrofuran 
• 1065271-50-2 (1'E,3'E,2S,3R,4S)-3-(tert-butyldiphenylsilanyloxy)-2-(tert-butyldiphenylsilanyloxymethyl)-4-(penta-1',3'-dienyl)tetrahydrofuran 
• 850166-90-4 4-[3-(4-methoxybenzyloxy)propyl]-2,2-dimethyl-5-(penta-1,3-dienyl)[1,3]dioxolane 
• 56374-57-3 <(E)-but-2-enylidene>triphenylphosphorane 
• 124994-21-4 (2S,3R)-2-Methyl-3-((1E,3E)-penta-1,3-dienyl)-1-(toluene-4-sulfonyl)-aziridine 

Relevant academic research and scientific papers

Remote Nucleophilic Allylation by Allylrhodium Chain Walking

Metal migration through a carbon chain is a versatile method for achieving remote functionalization. However, almost all known examples involve the overall net migration of alkylmetal species. Here, we report that allylrhodium species obtained from hydrorhodation of 1,3-dienes undergo chain walking toward esters, amides, or (hetero)arenes over distances of up to eight methylene units. The final, more highly conjugated allylrhodium species undergo nucleophilic allylation with aldehydes and with an imine to give Z-homoallylic alcohols and amines, respectively.

Streptopyridines, volatile pyridine alkaloids produced by Streptomyces sp. FORM5

Streptomyces sp. FORM5 is a bacterium that is known to produce the antibiotic streptazolin and related compounds. We investigated the strain for the production of volatiles using the CLSA (closed-loop stripping analysis) method. Liquid and agar plate cultures revealed the formation of new 2-alkylpyridines (streptopyridines), structurally closely related to the already known 2-pentadienylpiperidines. The structures of the streptopyridines A to E were confirmed by total synthesis. The analysis of the liquid phase by solvent extraction or extraction with an Oasis adsorbent showed that streptazolin and 2-pentadienylpiperidine are the major compounds, while the streptopyridines are only minor components. In the gas phase, only the streptopyridines could be detected. Therefore, an orthogonal set of analysis is needed to assess the metabolic profile of bacteria, because volatile compounds are obviously overlooked by traditional analytical methods. The streptopyridines are strain specific volatiles that are accompanied by a broad range of headspace constituents that occur in many actinomycetes. Volatiles might be of ecological importance for the producing organism, and, as biosynthetic intermediates or shunt products, they can be useful as indicators of antibiotic production in a bacterium.

Novel methodology for the preparation of five-, seven-, and nine-membered fused rings on C60

The photocycloaddition of dienyl cyclopropanes to C60 gives a new synthetic approach to yield stereospecifically five-, seven-, and nine-membered [60]fullerene adducts. Our results suggest the formation of a biradical intermediate between the dienyl substrate and C60. An electron transfer between the triplet excited state of C60 and the dienyl substrate precedes the formation of the intermediate.

Synthesis of 1-Acyl-2-alkylcyclopropanecarboxylic Esters from 2-Alkenylphosphonium Salts

The one-pot reaction of allyltriphenylphosphonium bromide with the sodium salts of β-keto esters leads to the formation of alkyl 1-acyl-2-alkylcyclopropanecarboxylates.