39746-60-6Relevant academic research and scientific papers
CYCLOADDITIONS OF 6-SILYLOXYFULVENES:ACCES TO 7-NORBORN-5-ENYL AND 7-NORBORNA-2,5-DIENYLALDEHYDES AND KETONES
Nzabamwita, Gaspard,Kolani, Bate,Jousseaume, Bernard
, p. 2207 - 2208 (2007/10/02)
Reactions of 6-silyloxy-6-alkyl-fulvenes with dimethyl acetylenedicarboxylate, maleic anhydride and 2-chloroacrylonitrile resulted in the formation of expected 7-substituted bicyclohepta-2,5-diene and hept-5-ene derivatives.Treatment of these adducts with Bu4NF produced the 7-norborn-5-enyl and 7-norborno-2,5-dienyl aldehydes and ketones in good yields.
