3978-58-3Relevant academic research and scientific papers
Method for stabilizing unsaturated organo-silicon compounds
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Page 7, (2008/06/13)
Process for stabilizing organosilicon compounds (II) containing an unsaturated group of the vinyl, acrylic ester or vinyl ether type, during production, distillation and/or storage, comprises preparing (II) by reacting a haloalkylsilane with a salt of an unsaturated organic acid in the presence of alkylene-bis(dialkylphenol) compounds (I). Process for stabilizing organosilicon compounds of formula (II) containing an unsaturated group of the vinyl, acrylic ester or vinyl ether type, during production, distillation and/or storage, comprises preparing (II) by reacting a haloalkylsilane with a salt of an unsaturated organic acid in the presence of alkylene-bis(dialkylphenol) compounds of formula (I); [Image] H2C=C(R4>)[C(O)O]w(O)x-(R5>)y-Si(R6>)z(OR7>)3-z (II); R4>H or linear or branched 1-10 C hydrocarbyl; R5>linear, cyclic or branched 1-40 C hydrocarbyl, optionally containing heteroatom(s) selected from N, O, S or P; R6>, R7>linear, cyclic or branched 1-10 C hydrocarbyl; w, x : 0 or, in one case only, 1; y : 0 or 1; z : 0, 1 or 2; R1>, R2>linear or branched 1-20 C alkyl; R3>H or linear or branched 1-20 C alkyl.
Process for stabilizing unsaturated organosilicon compounds
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Page 4-5, (2008/06/13)
A process for stabilizing organosilicon compounds bearing unsaturated groups during their preparation, distillation, and/or storage, the organosilicon compounds bearing unsaturated groups having been obtained by reacting a haloalkylsilane with a salt of an unsaturated organic acid, by adding one or more compounds of the formula I wherein R1 and R2 are identical or different linear or branched C1-20 alkyl, and the radicals R3 are identical or different and are hydrogen or linear or branched alkyl radicals having 1-20 carbon atoms.
The Hydrolysis/Condensation Behaviour of Methacryloyloxyalkylfunctional Alkoxysilanes: Structure-Reactivity Relations
Altmann, Stefan,Pfeiffer, Juergen
, p. 1081 - 1092 (2007/10/03)
Various methacryloyloxymethylalkoxysilanes have been synthesized by nucleophilic substitution reactions starting from chloromethylalkoxysilanes under phase transfer catalysis conditions. The compounds thus obtained show an exceptionally high degree of reactivity with regard to hydrolysis and condensation both under acidic as well as under basic conditions compared to the established 3-methacryloyloxypropyltrimethoxysilane. A mechanistic model for this high reactivity by intramolecular activation is discussed.
