Welcome to LookChem.com Sign In|Join Free
  • or

3982-91-0

Post Buying Request

3982-91-0 Suppliers

Recommended suppliersmore

Product FOB Price Min.Order Supply Ability Supplier

3982-91-0 Usage

Chemical Properties

clear colourless to slightly yellowish liquid

Air & Water Reactions

Fumes in air. Decomposes in water to form phosphoric acid and hydrochloric acid (hydrogen chloride). Both substances are corrosive to metal or tissue. Can also form hydrogen sulfide (H2S), a toxic flammable gas, in reaction with water [AAR 1991].

Fire Hazard

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Vapors may accumulate in confined areas (basement, tanks, hopper/tank cars etc.). Substance will react with water (some violently), releasing corrosive and/or toxic gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.

Safety Profile

Poison by inhalation. Moderately toxic by ingestion. A corrosive irritant to skin, eyes, and mucous membranes. Explosive reaction with methylmagnesium iodlde. Explosive reaction with pentaerythritol + heat. Reacts with water or steam to produce toxic and corrosive fumes. When heated to decomposition it emits highly toxic fumes of POx, SOx, and Cl-.

Purification Methods

Possible impurities are PCl5, H3PO4, HCl and AlCl3. Gently mix it with H2O to avoid a heavy emulsion; the product decoulorises immediately and settles to the bottom layer. It is soluble in *C6H6 and CCl4. [Duval Inorg Synth IV 73 1953.] HARMFUL VAPOURS.

Reactivity Profile

THIOPHOSPHORYL CHLORIDE is acidic. Incompatible with bases (including amines), with strong oxidizing agents, and with alcohols. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].

General Description

A colorless fuming liquid. Boiling point 257°F (125 °C). Irritates the eyes and mucous membranes. Corrosive to metals and tissue.

Hazard

Strong irritant to skin and tissue.

Health Hazard

TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
InChI:InChI=1/Cl3PS/c1-4(2,3)5

3982-91-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name THIOPHOSPHORYL CHLORIDE

1.2 Other means of identification

Product number -
Other names thiophosphoryl trichloride

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:3982-91-0 SDS

3982-91-0Synthetic route

sulfur
7704-34-9

sulfur

phosphorus trichloride
7719-12-2, 52843-90-0

phosphorus trichloride

trichlorothiophosphine
3982-91-0

trichlorothiophosphine

Conditions
ConditionsYield
With disulfur dichloride; iron(III) chloride In neat (no solvent) addn. of a mixt. of 140 g PCl3 and 1.7 g S2Cl2 drop by drop to a hot mixt. of 160 g PSCl3, 2 g anhydrous FeCl3 and 38 g S on stirring and refluxing (4.5 h); refluxing for 1 h, distg. off PSCl3;;100%
In neat (no solvent) react. molten S with PCl3 at 124-126 °C at ambient pressure; use of a catalyst formed on melting S with active carbon and boiling in PSCl3 at 200 °C;;
disulfur dichloride In not given react. with S2Cl2 as catalyst;;
barium sulfide

barium sulfide

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

A

trichlorothiophosphine
3982-91-0

trichlorothiophosphine

B

phosphorous (V) sulfide

phosphorous (V) sulfide

C

barium(II) chloride

barium(II) chloride

Conditions
ConditionsYield
In neat (no solvent) react. on heating under blazing up;;
calcium(II) sulfide

calcium(II) sulfide

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

A

trichlorothiophosphine
3982-91-0

trichlorothiophosphine

B

phosphorous (V) sulfide

phosphorous (V) sulfide

C

calcium chloride

calcium chloride

Conditions
ConditionsYield
In neat (no solvent) react. on heating under blazing up;;
phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

mercury sulfide

mercury sulfide

A

trichlorothiophosphine
3982-91-0

trichlorothiophosphine

B

phosphorous (V) sulfide

phosphorous (V) sulfide

C

mercury dichloride

mercury dichloride

Conditions
ConditionsYield
In neat (no solvent) byproducts: thiosulfate; react. on heating;;
thionyl chloride
7719-09-7

thionyl chloride

phosphorus

phosphorus

A

disulfur dichloride
10025-67-9

disulfur dichloride

B

trichlorothiophosphine
3982-91-0

trichlorothiophosphine

C

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

D

sulfur dioxide
7446-09-5

sulfur dioxide

E

phosphorus trichloride
7719-12-2, 52843-90-0

phosphorus trichloride

Conditions
ConditionsYield
In neat (no solvent) excess of SOCl2; 180°C;;
In neat (no solvent) excess of SOCl2; 180°C;;
sulfur dioxide
7446-09-5

sulfur dioxide

phosphorus trichloride
7719-12-2, 52843-90-0

phosphorus trichloride

A

trichlorothiophosphine
3982-91-0

trichlorothiophosphine

B

sulfur
7704-34-9

sulfur

Conditions
ConditionsYield
In neat (no solvent) byproducts: POCl3; decompn. of SO2- and PCl3-vapours in a calcinating tube;; formation of POCl3, PSCl3 and a small amount of S;;
In neat (no solvent) byproducts: POCl3; decompn. of SO2- and PCl3-vapours in a calcinating tube;; formation of POCl3, PSCl3 and a small amount of S;;
sulfur dioxide
7446-09-5

sulfur dioxide

phosphorus trichloride
7719-12-2, 52843-90-0

phosphorus trichloride

A

trichlorothiophosphine
3982-91-0

trichlorothiophosphine

Conditions
ConditionsYield
tetramethyl ammonium-pyrosulfite 50°C;
phosphorus tribromide 50°C;
phosphorus(V) oxybromide 50°C;
disulfur dichloride
10025-67-9

disulfur dichloride

tricalcium diphosphate

tricalcium diphosphate

A

trichlorothiophosphine
3982-91-0

trichlorothiophosphine

C

phosphorus trichloride
7719-12-2, 52843-90-0

phosphorus trichloride

Conditions
ConditionsYield
With silica gel In neat (no solvent) byproducts: SiCl4; react. of Ca3(PO4)2 with S2Cl2 at 1000 °C in presence of SiO2;; after 1 h 9.5 % phosphate are caused to react.;;
In neat (no solvent) react. of Ca3(PO4)2 with S2Cl2 at 1000 °C;; after 1 h 19.5 % phosphate are caused to react.;;
In neat (no solvent) react. of Ca3(PO4)2 with S2Cl2 at 1000 °C;; after 1 h 19.5 % phosphate are caused to react.;;
With SiO2 In neat (no solvent) byproducts: SiCl4; react. of Ca3(PO4)2 with S2Cl2 at 1000 °C in presence of SiO2;; after 1 h 9.5 % phosphate are caused to react.;;
disulfur dichloride
10025-67-9

disulfur dichloride

phosphorus

phosphorus

A

trichlorothiophosphine
3982-91-0

trichlorothiophosphine

B

sulfur
7704-34-9

sulfur

C

phosphorus trichloride
7719-12-2, 52843-90-0

phosphorus trichloride

Conditions
ConditionsYield
In neat (no solvent) addn. of P (excess) to boiling S2Cl2;;
disulfur dichloride
10025-67-9

disulfur dichloride

phosphorus

phosphorus

A

trichlorothiophosphine
3982-91-0

trichlorothiophosphine

B

sulfur
7704-34-9

sulfur

Conditions
ConditionsYield
In neat (no solvent) addn. of P to boiling S2Cl2;;
In neat (no solvent) react. at boiling temp.;;
With Fe or Al In neat (no solvent) heating P with S2Cl2 in presence of Fe or Al;;
In neat (no solvent) heating P with S2Cl2;;
thionyl chloride
7719-09-7

thionyl chloride

phosphorus trichloride
7719-12-2, 52843-90-0

phosphorus trichloride

A

trichlorothiophosphine
3982-91-0

trichlorothiophosphine

B

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

Conditions
ConditionsYield
In neat (no solvent) slowly at 80-160°C;; POCl3 only supposed;;
thionyl chloride
7719-09-7

thionyl chloride

phosphan
7803-51-2

phosphan

A

hydrogenchloride
7647-01-0

hydrogenchloride

B

trichlorothiophosphine
3982-91-0

trichlorothiophosphine

C

phosphorus

phosphorus

D

phosphorus sulfide
1314-85-8

phosphorus sulfide

Conditions
ConditionsYield
In neat (no solvent) room temp.;; further unidentified liquid products;;
thionyl chloride
7719-09-7

thionyl chloride

phosphorous (V) sulfide

phosphorous (V) sulfide

A

disulfur dichloride
10025-67-9

disulfur dichloride

B

trichlorothiophosphine
3982-91-0

trichlorothiophosphine

C

sulfur dioxide
7446-09-5

sulfur dioxide

D

phosphorus pentoxide

phosphorus pentoxide

E

sulfur
7704-34-9

sulfur

Conditions
ConditionsYield
In neat (no solvent) 100-150°C;;A 0%
B n/a
C n/a
D 0%
E n/a
In neat (no solvent) 100-150°C;;A 0%
B n/a
C n/a
D 0%
E n/a
thionyl chloride
7719-09-7

thionyl chloride

phosphorous (V) sulfide

phosphorous (V) sulfide

A

disulfur dichloride
10025-67-9

disulfur dichloride

B

trichlorothiophosphine
3982-91-0

trichlorothiophosphine

C

sulfur dioxide
7446-09-5

sulfur dioxide

D

sulfur
7704-34-9

sulfur

Conditions
ConditionsYield
In neat (no solvent) 100-150°C;;A 0%
B n/a
C n/a
D n/a
thionyl chloride
7719-09-7

thionyl chloride

phosphorous

phosphorous

A

disulfur dichloride
10025-67-9

disulfur dichloride

B

trichlorothiophosphine
3982-91-0

trichlorothiophosphine

C

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

D

sulfur dioxide
7446-09-5

sulfur dioxide

E

phosphorus trichloride
7719-12-2, 52843-90-0

phosphorus trichloride

Conditions
ConditionsYield
In neat (no solvent) excess of SOCl2; 180°C;;
In neat (no solvent) excess of SOCl2; 180°C;;
phosphorus trichloride
7719-12-2, 52843-90-0

phosphorus trichloride

trichlorothiophosphine
3982-91-0

trichlorothiophosphine

Conditions
ConditionsYield
With sulfur at 76°C, in common pressure;0%
With sulfur; barium sulfide in autoclave at 150°C for 4-5 h;>99
With sulfur; calcium(II) sulfide in autoclave at 150°C for 4-5 h;>99
disulfur dichloride
10025-67-9

disulfur dichloride

phosphorus trichloride
7719-12-2, 52843-90-0

phosphorus trichloride

A

trichlorothiophosphine
3982-91-0

trichlorothiophosphine

B

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

Conditions
ConditionsYield
In neat (no solvent) 6h, 160°C;;A >99
B >99
In neat (no solvent) 6h, 160°C;;A >99
B >99
sulfuryl dichloride
7791-25-5

sulfuryl dichloride

phosphorus trichloride
7719-12-2, 52843-90-0

phosphorus trichloride

A

trichlorothiophosphine
3982-91-0

trichlorothiophosphine

Conditions
ConditionsYield
In neat (no solvent) simultaneous formation of POCl3 and PSCl3 via reaction of PCl3 with SO2Cl2;; isolation via fractionation;;
In not given react. with SO2Cl2;; fractional distn.;;
In not given react. with SO2Cl2;; fractional distn.;;
disulfur dichloride
10025-67-9

disulfur dichloride

calcium metaphosphate

calcium metaphosphate

A

trichlorothiophosphine
3982-91-0

trichlorothiophosphine

C

phosphorus trichloride
7719-12-2, 52843-90-0

phosphorus trichloride

Conditions
ConditionsYield
With silica gel In neat (no solvent) byproducts: SiCl4; react. of Ca(PO3)2 with S2Cl2 at 1000 °C in presence of SiO2;;
With SiO2 In neat (no solvent) byproducts: SiCl4; react. of Ca(PO3)2 with S2Cl2 at 1000 °C in presence of SiO2;;
disulfur dichloride
10025-67-9

disulfur dichloride

phosphorus(III) oxide
12440-00-5

phosphorus(III) oxide

A

trichlorothiophosphine
3982-91-0

trichlorothiophosphine

B

sulfur dioxide
7446-09-5

sulfur dioxide

Conditions
ConditionsYield
In neat (no solvent) byproducts: S; vigorous reaction;;
disulfur dichloride
10025-67-9

disulfur dichloride

phosphorous

phosphorous

A

trichlorothiophosphine
3982-91-0

trichlorothiophosphine

B

sulfur
7704-34-9

sulfur

C

phosphorus trichloride
7719-12-2, 52843-90-0

phosphorus trichloride

Conditions
ConditionsYield
In neat (no solvent) in coldness under inflammation;;
phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

potassium thioacyanate
333-20-0

potassium thioacyanate

A

disulfur dichloride
10025-67-9

disulfur dichloride

B

trichlorothiophosphine
3982-91-0

trichlorothiophosphine

C

potassium chloride

potassium chloride

D

cyanogen chloride
506-77-4

cyanogen chloride

Conditions
ConditionsYield
In neat (no solvent) haeting at lower temp.; formation of CNCl, PSCl3, KCl and a small amount of S2Cl2;;
phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

potassium thioacyanate
333-20-0

potassium thioacyanate

A

trichlorothiophosphine
3982-91-0

trichlorothiophosphine

B

potassium chloride

potassium chloride

C

cyanogen chloride
506-77-4

cyanogen chloride

Conditions
ConditionsYield
heating;
heating;
lead(II) thiosulfate

lead(II) thiosulfate

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

A

trichlorothiophosphine
3982-91-0

trichlorothiophosphine

B

thionyl chloride
7719-09-7

thionyl chloride

C

lead(II) chloride

lead(II) chloride

Conditions
ConditionsYield
In neat (no solvent) heating PbS2O3 (dryed at 400 °C) with a reflux condenser; react. starting without heating, react. accelerated on heating; formation of POCl3, SOCl2, PSCl3 and PbCl2 as residue;;
phosphorous (V) sulfide

phosphorous (V) sulfide

A

trichlorothiophosphine
3982-91-0

trichlorothiophosphine

B

phosphoric acid
86119-84-8, 7664-38-2

phosphoric acid

Conditions
ConditionsYield
In neat (no solvent) react. with P2S5 in a sealing tube at 150 °C;;
In neat (no solvent) heating in a sealing tube at 150 °C;;
In neat (no solvent) react. with P2S5 in a sealing tube at 150 °C;;
phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

trichlorothiophosphine
3982-91-0

trichlorothiophosphine

Conditions
ConditionsYield
With metal sulfide In not given byproducts: metal chloride; react. with metal sulfides forming PSCl3 and corresponding metal chlorides;;
With hydrogen sulfide In neat (no solvent) byproducts: HCl; react. of dry H2S with PCl5 under heating;;
With hydrogen sulfide In neat (no solvent) byproducts: HCl;
With metal chloride In not given byproducts: metal sulfide; react. of PCl5 with metal chloride;;
With metal chloride In not given byproducts: metal sulfide; react. of PCl5 with metal chloride;;
thiophosphoryl(V) bromide
3931-89-3

thiophosphoryl(V) bromide

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

A

trichlorothiophosphine
3982-91-0

trichlorothiophosphine

B

phosphorus pentabromide
29679-77-4

phosphorus pentabromide

Conditions
ConditionsYield
In not given react. with PSBr3;;
In not given react. with PSBr3;;
phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

hydrogen sulfide
7783-06-4

hydrogen sulfide

trichlorothiophosphine
3982-91-0

trichlorothiophosphine

Conditions
ConditionsYield
In neat (no solvent) react. with liquid H2S;;
In carbon disulfide passing H2S through a liquid mixt. of PCl5 and CS2;; distn. in a stream of CO2;;
In not given react. of liquid H2S with PCl5;;
potassium sulfide

potassium sulfide

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

A

trichlorothiophosphine
3982-91-0

trichlorothiophosphine

B

potassium chloride

potassium chloride

C

phosphorous (V) sulfide

phosphorous (V) sulfide

Conditions
ConditionsYield
In neat (no solvent) react. on heating under blazing up;;
tin disulfide

tin disulfide

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

A

trichlorothiophosphine
3982-91-0

trichlorothiophosphine

B

phosphorous (V) sulfide

phosphorous (V) sulfide

C

tin(ll) chloride

tin(ll) chloride

Conditions
ConditionsYield
In neat (no solvent) byproducts: thiosulfate; react. on haeting;;
Conditions
ConditionsYield
In gas Kinetics; High Pressure; the reagent ions were generated in an electron impact high-pressure ion source contg. H2O; the reagent ions were selected using a quadrupole mass filter before being injected into a drift region contg. helium carriergas; at 298 K; monitoring by quadrupole mass spectrometer at the end of the flow tube;A 100%
B n/a
trichlorothiophosphine
3982-91-0

trichlorothiophosphine

water
7732-18-5

water

HPSCl3(1+)

HPSCl3(1+)

Conditions
ConditionsYield
In gas Kinetics; High Pressure; the reagent ions were generated in an electron impact high-pressure ion source contg. H2O; the reagent ions were selected using a quadrupole mass filter before being injected into a drift region contg. helium carriergas; at 298 K; monitoring by quadrupole mass spectrometer at the end of the flow tube;100%
trichlorothiophosphine
3982-91-0

trichlorothiophosphine

TamBP phenol

TamBP phenol

C42H72N3O21P7S

C42H72N3O21P7S

Conditions
ConditionsYield
With caesium carbonate In acetonitrile at 0 - 20℃; for 12h;98%
trichlorothiophosphine
3982-91-0

trichlorothiophosphine

sodium 3,5-bis(borane-diphenylphosphino)phenolate*2(tetrahydrofurane)

sodium 3,5-bis(borane-diphenylphosphino)phenolate*2(tetrahydrofurane)

chloro bis(3,5-bis(borane-diphenylphosphino)-phenoxy)thiophosphate
436805-36-6

chloro bis(3,5-bis(borane-diphenylphosphino)-phenoxy)thiophosphate

Conditions
ConditionsYield
In tetrahydrofuran byproducts: NaCl; in the absence of air using Schlenk techniques; mixed between -95 and -100°C under stirring; mixt. stirred overnight at room temp.; partially concd. (vac.); ppt. centrifuged; filtered under Ar; filtrate evapd; as oil;97.5%
trichlorothiophosphine
3982-91-0

trichlorothiophosphine

Nitrogen dioxide
10102-44-0

Nitrogen dioxide

A

OPSCl3(1+)

OPSCl3(1+)

B

NO*PSCl3(1+)

NO*PSCl3(1+)

C

nitrogen(II) oxide
10102-43-9

nitrogen(II) oxide

D

oxygen

oxygen

Conditions
ConditionsYield
In gas Kinetics; High Pressure; the reagent ions were generated in an electron impact high-pressure ion source contg. NO2; the reagent ions were selected using a quadrupole mass filter before being injected into a drift region contg. helium carriergas; at 298 K; monitoring by quadrupole mass spectrometer at the end of the flow tube;A 97%
B 3%
C n/a
D n/a
Conditions
ConditionsYield
In gas Kinetics; High Pressure; the reagent ions were generated in an electron impact high-pressure ion source contg. CO; the reagent ions were selected using a quadrupole massfilter before being injected into a drift region contg. helium carrier gas; at 298 K; monitoring by quadrupole mass spectrometer at the end of the flow tube;A n/a
B 93%
C 1%
D 6%
E n/a
Conditions
ConditionsYield
In gas Kinetics; High Pressure; the reagent ions were generated in an electron impact high-pressure ion source contg. N2O; the reagent ions were selected using a quadrupole mass filter before being injected into a drift region contg. helium carriergas; at 298 K; monitoring by quadrupole mass spectrometer at the end of the flow tube;A n/a
B 93%
C 1%
D 6%
E n/a
In gas Kinetics; byproducts: O; High Pressure; the reagent ions were generated in an electron impact high-pressure ion source contg. N2O; the reagent ions were selected using a quadrupole mass filter before being injected into a drift region contg. helium carriergas; at 298 K; O was also obtained; monitoring by quadrupole mass spectrometer at the end of the flow tube;A n/a
B 69%
C 18%
D 13%
E n/a
trichlorothiophosphine
3982-91-0

trichlorothiophosphine

ammonia
7664-41-7

ammonia

phosphorothioic triamide
55145-67-0, 13455-05-5

phosphorothioic triamide

Conditions
ConditionsYield
In chloroform dissolving NH3-gas at -10°C in dry CHCl3; dropwisre addn. of PSCl3 in CHCl3 during 1.5 h; passing NH3 through the soln. at -10°C; sucking off; drying in vac. and dissolving in CHCl3; boiling for 3-4 h in presence of diethylamine;; recrystn. from hot methanol;;90%
In chloroform dissolving NH3-gas at -10°C in dry CHCl3; dropwisre addn. of PSCl3 in CHCl3 during 1.5 h; passing NH3 through the soln. at -10°C; sucking off; drying in vac. and dissolving in CHCl3; boiling for 3-4 h in presence of diethylamine;; recrystn. from hot methanol;;90%
In not given formation from PSCl3 and NH3;;
trichlorothiophosphine
3982-91-0

trichlorothiophosphine

methylenebis(dichlorophosphine)
28240-68-8

methylenebis(dichlorophosphine)

methylene-bis-(phosphonic dichloride)
1499-32-7

methylene-bis-(phosphonic dichloride)

Conditions
ConditionsYield
With aluminum (III) chloride at 110 - 140℃; for 6h; Inert atmosphere;89%
trichlorothiophosphine
3982-91-0

trichlorothiophosphine

isopropyl alcohol
67-63-0

isopropyl alcohol

O-isopropyl phosphorodichloridothioate
19021-61-5

O-isopropyl phosphorodichloridothioate

Conditions
ConditionsYield
With pyridine at 20℃; for 2h;84%
trichlorothiophosphine
3982-91-0

trichlorothiophosphine

para-tert-butylphenol
98-54-4

para-tert-butylphenol

C10H13Cl2OPS
68591-35-5

C10H13Cl2OPS

Conditions
ConditionsYield
Stage #1: para-tert-butylphenol With sodium hydroxide In water at 0℃;
Stage #2: trichlorothiophosphine With tetrabutylammomium bromide In dichloromethane; water at 0 - 20℃; for 5h;
81%
Conditions
ConditionsYield
In gas Kinetics; byproducts: SCl, Cl2; High Pressure; the reagent ions were generated in an electron impact high-pressure ion source contg. N2; the reagent ions were selected using a quadrupole massfilter before being injected into a drift region contg. He; 298 K; SCl, Cl2 were also obtained; monitoring by quadrupole mass spectrometer at the end of the flow tube;A 80%
B 4%
C 2%
D 14%
E n/a
trichlorothiophosphine
3982-91-0

trichlorothiophosphine

carbon dioxide
124-38-9

carbon dioxide

A

sulphur monochloride
14989-32-3

sulphur monochloride

B

PSCl2(1+)
52826-97-8

PSCl2(1+)

C

PSCl3(1+)

PSCl3(1+)

D

O2*PSCl2(1+)

O2*PSCl2(1+)

E

PCl2(1+)
75601-84-2

PCl2(1+)

Conditions
ConditionsYield
In gas Kinetics; byproducts: Cl, CCl; High Pressure; the reagent ions were generated in an electron impact high-pressure ion source contg. CO2; the reagent ions were selected using a quadrupole mass filter before being injected into a drift region contg. He; at 298 K; Cl, CCl were also obtained; monitoring by quadrupole mass spectrometer at the end of the flow tube;A n/a
B 80%
C 11%
D 3%
E 6%
trichlorothiophosphine
3982-91-0

trichlorothiophosphine

ortho-cresol
95-48-7

ortho-cresol

2-methylpheylphosphorodichloridate
91674-47-4

2-methylpheylphosphorodichloridate

Conditions
ConditionsYield
Stage #1: ortho-cresol With sodium hydroxide In water at 0℃;
Stage #2: trichlorothiophosphine With tetrabutylammomium bromide In dichloromethane; water at 0 - 20℃; for 5h;
80%
trichlorothiophosphine
3982-91-0

trichlorothiophosphine

p-cresol
106-44-5

p-cresol

p-tolyl phosphorodichloridothionate
18961-95-0

p-tolyl phosphorodichloridothionate

Conditions
ConditionsYield
Stage #1: p-cresol With sodium hydroxide In water at 0℃;
Stage #2: trichlorothiophosphine With tetrabutylammomium bromide In dichloromethane; water at 0 - 20℃; for 5h;
76%
trichlorothiophosphine
3982-91-0

trichlorothiophosphine

2-fluorophenol
367-12-4

2-fluorophenol

C6H4Cl2FOPS
1428326-54-8

C6H4Cl2FOPS

Conditions
ConditionsYield
Stage #1: 2-fluorophenol With sodium hydroxide In water at 0℃;
Stage #2: trichlorothiophosphine With tetrabutylammomium bromide In dichloromethane; water at 0 - 20℃; for 8h;
75%
Conditions
ConditionsYield
In gas Kinetics; High Pressure; the reagent ions were generated in an electron impact high-pressure ion source contg. O2/N2; the reagent ions were selected using a quadrupole mass filter before being injected into a drift region contg. helium carrier gas; at 298 K; monitoring by quadrupole mass spectrometer at the end of the flow tube;A 21%
B 73%
C 6%
D n/a
trichlorothiophosphine
3982-91-0

trichlorothiophosphine

2-monochlorophenol
95-57-8

2-monochlorophenol

phosphorodichloridothioic acid O-ortho-chlorophenyl ester
68591-34-4

phosphorodichloridothioic acid O-ortho-chlorophenyl ester

Conditions
ConditionsYield
Stage #1: 2-monochlorophenol With sodium hydroxide In water at 0℃;
Stage #2: trichlorothiophosphine With tetrabutylammomium bromide In dichloromethane; water at 0 - 20℃; for 8h;
72%
trichlorothiophosphine
3982-91-0

trichlorothiophosphine

carbon tetrafluoride
75-73-0

carbon tetrafluoride

A

PSCl2(1+)
52826-97-8

PSCl2(1+)

B

CF2Cl3(1+)

CF2Cl3(1+)

C

PSCl3(1+)

PSCl3(1+)

D

Cl3FP(1+)
64710-27-6

Cl3FP(1+)

E

PCl3(1+)

PCl3(1+)

Conditions
ConditionsYield
In gas Kinetics; byproducts: CF2, CF2S, CClF2; High Pressure; ions were generated in an electron impact high-pressure ion source contg. CF4; the reagent ions were selected using a quadrupole mass filter before being injected into a region contg. He; at 298 K; CF2, CF2S, CClF2, CFS, PS were obtained; monitoring by quadrupole mass spectrometer at the end of the flow tube;A 4%
B 2%
C 69%
D n/a
E 25%
trichlorothiophosphine
3982-91-0

trichlorothiophosphine

sulfur(VI) hexafluoride
2551-62-4

sulfur(VI) hexafluoride

A

ClS2(1+)
80799-96-8

ClS2(1+)

B

PSCl2(1+)
52826-97-8

PSCl2(1+)

C

PSCl3(1+)

PSCl3(1+)

D

Cl3FP(1+)
64710-27-6

Cl3FP(1+)

E

PCl3(1+)

PCl3(1+)

Conditions
ConditionsYield
In gas Kinetics; byproducts: S2(1+), PFCl3, F; High Pressure; ions generated in an electron impact high-pressure ion source contg. SF6were selected using a quadrupole mass filter before being injected into a region contg. He; 298 K; S*PSCl3(1+), SF, SFCl, S2, ClF, ClP, FS2, S2 (1+), PFCl3, F were also obtained; monitoring by quadrupole mass spectrometer at the end of the flow tube;A 4%
B 14%
C 69%
D 6%
E 3%
trichlorothiophosphine
3982-91-0

trichlorothiophosphine

sulfur(VI) hexafluoride
2551-62-4

sulfur(VI) hexafluoride

A

FS2(1+)
43431-44-3

FS2(1+)

B

PSCl3(1+)

PSCl3(1+)

C

S*PSCl3(1+)

S*PSCl3(1+)

D

Cl3FP(1+)
64710-27-6

Cl3FP(1+)

E

PCl3(1+)

PCl3(1+)

Conditions
ConditionsYield
In gas Kinetics; byproducts: SF2, F2, PFCl3; High Pressure; the ions were generated in an electron impact high-pressure ion source contg. SF6; the ions were selected using a quadrupole mass filter before being injected into a drift region contg. He carrier gas; 298 K; SF2, F2, PFCl3, FS2, SSF2 were also obtained; monitoring by quadrupole mass spectrometer at the end of the flow tube;;A 8%
B 66%
C 13%
D 8%
E 5%
trichlorothiophosphine
3982-91-0

trichlorothiophosphine

sodium hydroxide
1310-73-2

sodium hydroxide

trisodium thiophosphate

trisodium thiophosphate

Conditions
ConditionsYield
In water at 3 - 95℃; for 2.66667h; Product distribution / selectivity; Heating / reflux;65%
trichlorothiophosphine
3982-91-0

trichlorothiophosphine

carbon tetrafluoride
75-73-0

carbon tetrafluoride

A

PFCl2(1+)

PFCl2(1+)

B

SCF(1+)
38264-02-7

SCF(1+)

C

PCl2(1+)
75601-84-2

PCl2(1+)

D

PS(1+)
81128-92-9

PS(1+)

E

fluorodichloromethyl(1+)
40640-70-8

fluorodichloromethyl(1+)

Conditions
ConditionsYield
In gas Kinetics; byproducts: CFSCl3(1+), PFCl3(1+), CClS(1+); High Pressure; ions generated in an electron impact high-pressure source contg. CF4 were selected using a mass filter before being injected into a region contg. He; 298 K; CFSCl3(1+), PFCl3(1+), CClS(1+), CCl3F, PCl3, CClS, CClFS, PSCl, P, CS, PFCl2 were also obtained; monitoring by quadrupole mass spectrometer at the end of the flow tube;A 15%
B 64%
C n/a
D n/a
E 9%
trichlorothiophosphine
3982-91-0

trichlorothiophosphine

nitrogen
7727-37-9

nitrogen

A

PSCl2(1+)
52826-97-8

PSCl2(1+)

B

PSCl(1+)

PSCl(1+)

C

PSCl3(1+)

PSCl3(1+)

D

PCl2(1+)
75601-84-2

PCl2(1+)

E

NS(1+)

NS(1+)

Conditions
ConditionsYield
In gas Kinetics; byproducts: Cl, N, PS(1+); High Pressure; ions generated in an electron impact high-pressure source contg. N2 wereselected using a quadrupole mass filter before being injected into a dr ift region contg. He; at 298 K; PS(1+), Cl, N, SCl, PCl3, Cl2, NCl3 werealso obtained; monitoring by quadrupole mass spectrometer at the end of the flow tube;A 62%
B 1%
C 16%
D 15%
E 5%
trichlorothiophosphine
3982-91-0

trichlorothiophosphine

ammonium chloride
12125-02-9

ammonium chloride

dichlorothiophosphoric acid amide
14475-36-6, 34859-01-3

dichlorothiophosphoric acid amide

Conditions
ConditionsYield
for 20h; Reflux;58.5%
trichlorothiophosphine
3982-91-0

trichlorothiophosphine

sodium hydroxide
1310-73-2

sodium hydroxide

trisodium thiophosphate

trisodium thiophosphate

Conditions
ConditionsYield
In water for 0.5h; Product distribution / selectivity; Reflux;56.5%
In water according to S.K. Yasuda, J.L. Lambert, Inorg. Synth. 1957, 5, 102; PSCl3 added to aq. NaOH; suspended in anhydr. methanol;42%
In neat (no solvent)
In neat (no solvent)
In water react. of aq. NaOH and PSCl3;
trichlorothiophosphine
3982-91-0

trichlorothiophosphine

hydroxyferrocene

hydroxyferrocene

A

diferrocenyl chlorothiophosphonate
206068-79-3

diferrocenyl chlorothiophosphonate

B

triferrocenyl thiophosphate

triferrocenyl thiophosphate

Conditions
ConditionsYield
With NEt3 In tetrahydrofuran byproducts: NEt3HCl; Ar-atmosphere; mixing equimolar amt. of ferrocene derivative and NEt3, cooling to -78°C, slow addn. of 0.5 equiv. of PSCl3, stirring (room temp., overnight); filtration, evapn. (vac.), chromy. (SiO2, CH2Cl2);A 49%
B n/a
trichlorothiophosphine
3982-91-0

trichlorothiophosphine

carbon tetrafluoride
75-73-0

carbon tetrafluoride

A

PSCl2(1+)
52826-97-8

PSCl2(1+)

B

CF3(1+)*PSCl3=CF3*PSCl3(1+)

CF3(1+)*PSCl3=CF3*PSCl3(1+)

C

Cl3FP(1+)
64710-27-6

Cl3FP(1+)

D

thiocarbonyl fluoride
420-32-6

thiocarbonyl fluoride

E

chlorotrifluoromethane
75-72-9

chlorotrifluoromethane

Conditions
ConditionsYield
In gas Kinetics; High Pressure; the reagent ions were generated in an electron impact high-pressure ion source contg. CF4; the reagent ions were selected using a quadrupole mass filter before being injected into a drift region contg. helium carriergas; at 298 K; monitoring by quadrupole mass spectrometer at the end of the flow tube;A 48%
B 44%
C 8%
D n/a
E n/a
trichlorothiophosphine
3982-91-0

trichlorothiophosphine

dinitrogen monoxide
10024-97-2

dinitrogen monoxide

A

PSCl2(1+)
52826-97-8

PSCl2(1+)

B

PSCl3(1+)

PSCl3(1+)

C

NO*PSCl3(1+)

NO*PSCl3(1+)

D

PCl2(1+)
75601-84-2

PCl2(1+)

E

nitrogen(II) oxide
10102-43-9

nitrogen(II) oxide

Conditions
ConditionsYield
In gas Kinetics; byproducts: ClNOS, ClNO; High Pressure; the reagent ions were generated in an electron impact high-pressure ion source contg. N2O; the reagent ions were selected using a quadrupole mass filter before being injected into a region contg. He; at 298 K; ClNO, ClNOS were also obtained; monitoring by quadrupole mass spectrometer at the end of the flow tube;A 7%
B 47%
C 33%
D 13%
E n/a
Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 3982-91-0