39847-43-3

Upstream product

• 186581-53-3 diazomethane 
• 39847-39-7 bis(nonafluorobutanesulfonyl)imide 
• 77-78-1 dimethyl sulfate 
• 616-38-6 carbonic acid dimethyl ester 
• 1445-45-0 Trimethyl orthoacetate 

Relevant academic research and scientific papers

Design of Electrophoretic and Biocompatible Poly(2-oxazoline)s Initiated by Perfluoroalkanesulfoneimides and Electrophoretic Deposition with Bioactive Glass

N-Methyl bis[(nonafluorobutane)sulfonyl]imide (Nf2NMe) was synthesized to serve as an initiator for polymerization of 2-oxazolines and the polymerization activity and control of molecular weight were compared with conventional methyl triflate (TfOMe). Ring-opening polymerization of the vinyl-containing 2-oxazoline, 2-(3-butenyl)-2-oxazoline, and a subsequent thiol-ene click reaction and oxidation resulted in the successful synthesis of electrophoretic poly(2-oxazoline)s containing pendent sulfone. It was possible to coat the polymeric sulfones obtained via oxone oxidation (conversion, >99%) on a stainless-steel anode selectively. Furthermore, hybridization of the poly(2-oxazoline)s with bioactive glass (Bioglass45S5) by electrophoretic deposition (EPD) was investigated, and the biocompatibility of the hybrid was also evaluated. (Figure Presented)

FLUORINE-CONTAINING N-ALKYLSULFONYLIMIDE COMPOUND, MANUFACTURING METHOD THEREFOR, AND METHOD OF MANUFACTURING AN IONIC COMPOUND

According to the method for producing fluorine-containing N-alkylsulfonylimide compound, the fluorine-containing N-alkylsulfonylimide compound can be produced safely with a high recovery rate by alkylating fluorine-containing sulfonylimide acid or fluorine-containing sulfonylimide acid salt with dialkylsulfuric acid or dialkylcarbonic acid.

Direct methylation and trifluoroethylation of imidazole and pyridine derivatives

Direct methylation or trifluoroethylation of imidazole and pyridine derivatives using N-methyl bis((perfluoroalkyl)sul-fonyl)imides or trifluoroethyl phenyliodonium bis((trifluoromethyl)sulfonyl)imide affords high yields of the corresponding salts. This methodology provides a simple route to a variety of room temperature ionic liquids (RTILs).