39895-70-0Relevant academic research and scientific papers
Kinetics of the Tungstate-catalyzed H2O2 Oxidation of Amines in Aqueous Methanol. Acidity Effect
Ogata, Yoshiro,Tomizawa, Kohtaro,Maeda, Hirokazu
, p. 285 - 286 (1980)
Oxidation of N,N-dimethylaniline and benzylamine with H2O2 catalyzed by Na2WO4 has been kinetically studied in buffered 50 percent aqueous methanol at 25 deg C.The rates with a catalytic amount of Na2WO4 fit Eq.: v = ktt0 and the pH profile of rate constant shows no dissociation of peroxotungstate at pH 5-10.N,N-Dimethylaniline gives N-oxide (73percent) and benzylamine gives benzaldehyde oxime (65percent) under the present kinetic conditions.
