39896-94-1Relevant articles and documents
The direct reductive amination of electron-deficient amines with aldehydes: The unique reactivity of the Re2O7 catalyst
Das, Braja Gopal,Ghorai, Prasanta
supporting information; experimental part, p. 8276 - 8278 (2012/09/22)
An unprecedented direct reductive amination of electron-deficient amines such as Cbz-, Boc-, EtOCO-, Fmoc-, Bz-, ArSO2-, Ar2PO-, etc. protected amines with aldehydes is achieved using the Re2O 7 catalyst and silanes as the hydride source. Excellent regioselective mono-alkylation and chemoselective reductive-amination were observed.