39938-06-2

Upstream product

• 515-42-4 sodium phenylsulfonate 
• 98-11-3 benzenesulfonic acid 

Downstream Products

• 115400-13-0 p-nitrophenacyl benzenesulphonate 
• 1315270-52-0 C₆H₅O₃S^(1-)*C₁₉H₂₅N₂O⁽¹⁺⁾ 
• 1315270-40-6 C₆H₅O₃S^(1-)*C₁₉H₂₅N₂O₃⁽¹⁺⁾ 
• 84855-92-5 3-cyclohexylmethyl-2-oxopentyl benzenesulfonate 
• 127-63-9 diphenyl sulphone 
• 38632-84-7 benzyl benzenesulfonate 
• 31997-69-0 Benzoic acid benzenesulfonyloxymethyl ester 

Relevant academic research and scientific papers

A layered silver sulfonate incorporating nine-coordinate Ag(I) in a hexagonal grid

Silver benzenesulfonate is an example of a layered 'inorgano-organic' solid where the inorganic component is comprised of sulfonate-bridged silver(I) centers and the organic moiety is a phenyl group; the resulting network of silver ions forms a planar hexagonal array incorporating a previously unobserved six-fold metal-bridging mode for the sulfonate ion.

Sulfosilylation of Aromatic Hydrocarbons by Trimethylsilyl Chlorosulfonate

Aromatic hydrocarbons 2 ,6 ,8 ,9 ,13 ,16 ,18 ,19 ,22 react with trimethylsilyl chlorosulfonate (1) to give trimethylsilyl arenesulfonates 5, 7, 11, 12, 15, 23 or sulfonic acids 17, 20, 21.If trimethylsilyl sulfonates are obtained, working up of the sulfonation mixtures is possible by distillation.By hydrohalogenolysis of trimethylsilyl sulfonates 5 at 0-5 deg C anhydrous sulfonic acids 3 result.The pathways to diphenylsulfone (25a) in the reaction of benzene (2a) with 1 were investigated.In this connection we succeeded in synthesizing benzenepyrosulfonic acid (28) and trimethylsilyl benzenepyrosulfonate (29).