39960-97-9

Upstream product

• 79-36-7 dichloroacethyl chloride 
• 3306-06-7 (+/-)-threo-2-amino-1-phenyl-1,3-propanediol 
• 116-54-1 dichloroacetic acid methyl ester 
• 513-96-2 3,3,3-trichloro-2-hydroxy-propionitrile 
• 3306-06-7 (1RS,2SR)-2-amino-1-phenyl-propane-1,3-diol 
• 3018-12-0 dichloroacetonitrile 

Downstream Products

• 33485-03-9 (1RS,2RS)-2-(2,2-dichloro-acetylamino)-1-(4-nitro-phenyl)-1,3-bis-nitryloxy-propane 
• 97407-57-3 (1RS,2RS)-1,3-diacetoxy-2-(2,2-dichloro-acetylamino)-1-phenyl-propane 
• 56-75-7 chlorampenicol 
• 97407-57-3 (1RS:2SR)-2-(C.C-dichloro-acetylamino)-1.3-diacetoxy-1-phenyl-propane 
• 119-62-0 (1RS,2SR)-2-amino-1-(4-nitro-phenyl)-propane-1,3-diol 
• 56-75-7 2-(2,2-dichloroacetylamino)-1-(4-nitrophenyl)propane-1,3-diol 
• 10318-17-9 (1RS,2SR)-1,3-diacetoxy-2-(2,2-dichloro-acetylamino)-1-(4-nitro-phenyl)-propane 
• 10318-17-9 (1RS,2RS)-1,3-diacetoxy-2-(2,2-dichloro-acetylamino)-1-(4-nitro-phenyl)-propane 

Relevant academic research and scientific papers

Oxidant controlled regio- and stereodivergent azidohydroxylation of alkenes via I2 catalysis

A novel, I2 catalyzed regio- and stereodivergent vicinal azidohydroxylation of alkenes leading to 1,2-azidoalcohols in high yields (up to 92%) and excellent dr (up to 98%) has been developed. This unprecedented transformation employs NaN3 and DMF as N- and O-nucleophiles respectively. The role of DMF as the O-source in the reaction has been unequivocally proven by 18O labelling studies.