400053-84-1Relevant academic research and scientific papers
Synthesis of blastidic acid and cytosinine, two components of blasticidin S
Ichikawa,Ohbayashi,Hirata,Nishizawa,Isobe
, p. 1763 - 1766 (2001)
Blastidic acid and cytosinine, two components of antibiotics blasticidin S, have been synthesized.
Total synthesis of (+)-blasticidin S
Ichikawa, Yoshiyasu,Hirata, Keiko,Ohayashi, Masayoshi,Isobe, Minoru
, p. 3241 - 3251 (2007/10/03)
The first total synthesis of the peptidyl nucleoside antibiotic, blasticidin S (1), has been achieved by the coupling reaction of cytosinine (3) and blastidic acid (2). A key step in the synthesis of cytosinine (3) is the sigma-tropic rearrangement of all
