400723-11-7

Basic information

• Product Name: 2,4,6-Heptatrien-1-one, 1-(4-methoxyphenyl)-6-methyl-7,7-bis(methylthio)-, (2E,4E)-
• CAS NO: 400723-11-7
• Molecular Formula: C17H20O2S2
• Molecular Weight: 320.477
• Mol File: 400723-11-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,4,6-Heptatrien-1-one, 1-(4-methoxyphenyl)-6-methyl-7,7-bis(methylthio)-, (2E,4E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4,6-Heptatrien-1-one, 1-(4-methoxyphenyl)-6-methyl-7,7-bis(methylthio)-, (2E,4E)-(400723-11-7)
• EPA Substance Registry System: 2,4,6-Heptatrien-1-one, 1-(4-methoxyphenyl)-6-methyl-7,7-bis(methylthio)-, (2E,4E)-(400723-11-7)

Safety Data

• Hazardous Substances Data: 400723-11-7(Hazardous Substances Data)

Upstream product

• 17649-87-5 3-methyl-4,4-bis(methylthio)but-3-en-2-one 
• 15081-13-7 3-methyl-4,4-bis-methylsulfanyl-but-3-en-2-ol 
• 129611-81-0 5,5-bis(methylthio)-4-methyl-2,4-pentadienal 
• 100-06-1 1-(4-methoxyphenyl)ethanone 

Relevant articles and documents

A new 1,5- to 1,11-carbonyl transposition protocol involving ketene dithioacetal chemistry: An efficient polyene synthesis

An efficient strategy for alternative 1,5-, 1,7-, 1,9- and 1,11- carbonyl transposition has been developed via 1,2-reductive or alkylative addition to 5,5-bis(methylthio)-2,4-pentadienals 3a-b, 7,7-bis(methylthio)-2,4,6-heptatrienones 5,9,9-bis(methylthio)-2,4,6,8-nonatetraenones 8 and 11,11-bis(methylthio)-2,4,6,8,10-undecapentaenones 11 followed by BF3,Et2O induced methanolysis of the resulting carbinols to the corresponding polyene esters. The synthesis of the novel polyene aldehydes 3a-b, 7a-b, 10b and polyenones 5, 8, 11 precursors has also been described following iterative Vielsmeier-Haack reaction and aldol condensation.