400828-03-7

Basic information

• Product Name: ETHYL (Z)-2-ACETYL-5-PHENYL-2-[(Z)-3-PHENYL-2-PROPENYL]-4-PENTENOATE
• Synonyms: ETHYL (Z)-2-ACETYL-5-PHENYL-2-[(Z)-3-PHENYL-2-PROPENYL]-4-PENTENOATE;ethyl (4Z)-2-acetyl-5-phenyl-2-[(2Z)-3-phenylprop-2-en-1-yl]pent-4-enoate
• CAS NO: 400828-03-7
• Molecular Formula: C24H26O3
• Molecular Weight: 362.46
• Mol File: 400828-03-7.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: ETHYL (Z)-2-ACETYL-5-PHENYL-2-[(Z)-3-PHENYL-2-PROPENYL]-4-PENTENOATE(CAS DataBase Reference)
• NIST Chemistry Reference: ETHYL (Z)-2-ACETYL-5-PHENYL-2-[(Z)-3-PHENYL-2-PROPENYL]-4-PENTENOATE(400828-03-7)
• EPA Substance Registry System: ETHYL (Z)-2-ACETYL-5-PHENYL-2-[(Z)-3-PHENYL-2-PROPENYL]-4-PENTENOATE(400828-03-7)

Safety Data

• Hazardous Substances Data: 400828-03-7(Hazardous Substances Data)

Upstream product

• 106625-69-8 ethyl (E)-3-phenyl-2-propenyl carbonate 
• 141-97-9 ethyl acetoacetate 
• 4392-24-9 Cinnamyl bromide 
• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 
• 21040-45-9 Cinnamyl acetate 
• 2723-42-4 ethyl 3-pyrrolidinobut-2-enoate 
• 21087-29-6 trans-3-phenylprop-2-enyl chloride 
• 1007476-32-5 sodium ethyl acetylacetate enolate 

Relevant articles and documents

Dual platinum and pyrrolidine catalysis in the direct alkylation of allylic alcohols: Selective synthesis of monoallylation products

A dual platinum- and pyrrolidine-catalyzed direct allylic alkylation of allylic alcohols with various active methylene compounds to produce products with high monoallylation selectivity was developed. The use of pyrrolidine and acetic acid was essential, not only for preventing undesirable side reactions, but also for obtaining high monoallylation selectivity. Two cats are better than one: The combined use of platinum and pyrrolidine catalysts enabled the direct alkylation of allylic alcohols with reactive methylene compounds. Pyrrolidine was essential for obtaining high selectivity of the monoallylation products, which were produced without the use of excess nucleophiles. cod=1,5- cyclooctadiene, EWG=electron-withdrawing group.

(π-Allyl)palladium complexes bearing diphosphinidenecyclobutene ligands (DPCB): Highly active catalysts for direct conversion of allylic alcohols

The (π-allyl)palladium complex bearing an sp2-hybridized phosphorus ligand (DPCB-OMe: 1,2-bis(4-methoxyphenyl)-3,4-bis[(2,4,6-tri-tert-butylphenyl)phosphinidene]cyclobutene) efficiently catalyzes direct conversion of allylic alcohols in the absence of activating agents of alcohols such as Lewis acids. N-Allylation of aniline proceeds at room temperature to afford monoallylated anilines in 90-97% yields. C-Allylation of active methylene compounds is also successful at 50 °C using a catalytic amount of pyridine as a base, giving monoallylation products in 85-95% yields. The catalytic mechanism involving hydrido- and (π-allyl)palladium intermediates has been proposed on the basis of stoichiometric examinations using model compounds of presumed intermediates. Copyright

Palladium(0)-Catalyzed Substitution of Allylic Substrates in an Aqueous-Organic Medium

A palladium(0)-water soluble catalyst prepared in situ from palladium acetate and the sulfonated triphenyl phosphine P(C6H4-m-SO3Na)3 (or tppts) is an efficient catalyst for allylic substitution with various carbon and heteronucleophiles in an aqueous-organic medium, allowing a very easy separation of the product(s) and the recycling of the catalyst.