400835-41-8Relevant academic research and scientific papers
Synthesis and structure of the first neutral octahedral cis-dioxorhenium(V) complex
Bandoli, Giuliano,Dolmella, Alessandro,Gerber, Thomas I.A.,Luzipo, Dibanisile,Du Preez, Jan G.H.
, p. 215 - 219 (2001)
The complex cis-[ReO2(Hdab)(py)2] (1) (H2dab = 1,2-diaminobenzene) has been prepared by reacting trans-[ReO2(py)4]I with H2dab in ethanol. This is the first example of a neutral hexacoordinate rhenium(V) complex with a cis arrangement of the two oxo groups. The compound also provides the first example of a bidentate monoanionic monoimino coordination mode of H2dab. Crystal data for 1·(H3dab)I·H2O: C22H26IN6O2Re·H 2O, triclinic, space group P1?, a = 9.570(2), b = 12.493(3), c = 12.851(3) A?, α = 61.60(3), β = 70.56(3), γ = 78.68(4)°, V = 1273.1(4) A?3 and Z = 2.
