40093-52-5

Upstream product

• 696-62-8 para-iodoanisole 
• 5331-43-1 N-benzyloxycarbonyl-hydrazine 

Downstream Products

• 1197055-22-3 benzyl 5-methoxy-3-(2-methoxy-2-oxoethyl)-2-methyl-1H-indole-1-carboxylate 
• 1197055-31-4 benzyl 6-methoxy-3,4-dihydro-1H-carbazole-9(2H)-carboxylate 
• 1197055-18-7 benzyl 5-methoxy-2,3-dimethyl-1H-indole-1-carboxylate 
• 1268268-38-7 benzyl 2-(2-aminonaphthalen-1-yl)-4-methoxyphenylcarbamate 
• 1268268-20-7 benzyl 1-(4-methoxyphenyl)-2-(naphthalen-2-yl)hydrazinecarboxylate 

Relevant academic research and scientific papers

Asymmetric NHC-catalyzed redox α-amination of α- aroyloxyaldehydes

Asymmetric α-amination through an N-heterocyclic carbene (NHC)-catalyzed redox reaction of α-aroyloxyaldehydes with N-aryl-N-aroyldiazenes to form α-hydrazino esters with high enantioselectivity (up to 99% ee) is reported. The hydrazide products are readily converted into enantioenriched N-aryl amino esters through samarium(II) iodide mediated N-N bond cleavage.

Aryl hydrazide beyond as surrogate of aryl hydrazine in the Fischer indolization: The synthesis of N-Cbz-indoles, N-Cbz-carbazoles, and N,N-Bis-Cbz-pyrrolo[2,3-f]indoles

"Chemical Equation Presented" Aryl hydrazides underwent the Fischer indolizatlon reactions, while the N-carbamate group(s) remained intact to directly provide N-Cbz-indoles. This new method allowed the synthesis of various N-Cbz-carbazoles and N,N-bis-Cbz