4011-48-7Relevant articles and documents
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Dreiding et al.
, p. 3159 (1953)
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A (2)H N.M.R. study of the Steroidal Dienone-Phenol Rearrangement
Avent, Antony G.,Hanson, James R.,Yang-zhi, Ling,Sadler, Ian H.
, p. 2129 - 2132 (2007/10/02)
The extent of deuteriation is reported for the products of the dienone-phenol rearrangement of androsta-1,4-dien-3-ones using as catalysts (i) deuteriated acetic anhydride, acetic acid, and zinc chloride; (ii) deuterium bromide; and (iii) methanol, ethyl orthoformate, and sulphuric acid.The stereochemistry of the acid-catalysed enolization of 1-dehydrotestosterone is also reported.