40148-85-4Relevant academic research and scientific papers
Mapping the potential energy surface of the tolylcarbene rearrangement in the inner phase of a hemicarcerand
Kerdelhue, Jean-Luc,Langenwalter, Kevin J.,Warmuth, Ralf
, p. 973 - 986 (2003)
Photolysis of p-tolyldiazirine (6) in the inner phase of a hemicarcerand with four butane-1,4-dioxy linker groups (5) in C6D5CD3 at 77 K yields the 5-methylcycloheptatetraene hemicarceplex 5>=3b in 41% together with innerm
Rearrangements of the Isomeric Tolylmethylenes
Chapman, Orville L.,Johnson, Jeffery W.,Mahon, Robert J. Mc,West, Paul R.
, p. 501 - 509 (2007/10/02)
We present evidence for a mechanism in which the isomeric tolylmethylenes interconvert via methylcycloheptatetraene intermediates.Photolysis (>470 nm) of diazo compounds 1-4, matrix isolated in argon at 10 K, generates triplet tolylmethylenes 8-11.Photoly
