401513-52-8Relevant academic research and scientific papers
Kinetic Resolution of α-Silyl-Substituted Allylboronate Esters via Chemo- and Stereoselective Allylboration of Aldehydes
Park, Jinyoung,Jung, Yongsuk,Kim, Jeongho,Lee, Eunsung,Lee, Sarah Yunmi,Cho, Seung Hwan
, p. 2371 - 2376 (2021)
We describe the kinetic resolution of α-silyl-substituted allylboronate esters via chiral phosphoric acid-catalyzed chemo-, diastereo- and enantioselective allylboration of aldehydes. This process provides two synthetically versatile enantioenriched compo
1-Silyl-1-boryl-2-alkenes: Reagents for stereodivergent allylation leading to 4-oxy-(E)-1-alkenylboronates and 4-oxy-(Z)-1-alkenylsilanes
Shimizu, Masaki,Kitagawa, Hirotaka,Kurahashi, Takuya,Hiyama, Tamejiro
, p. 4283 - 4286 (2007/10/03)
Silylboryl reagents for organic synthesis: 1-silyl-1-boryl-2-alkenes (2) were prepared efficiently by gem-silylborylation of α-chloroallyllithium compounds from (dimethylphenylsilyl) (pinacolato)borane (1; see scheme, LDA = lithium diisopropylamide) and w
