40155-10-0

Basic information

• Product Name: (3S,5S,7S)-adamantan-1-yl 2-phenylacetate
• Synonyms: (3S,5S,7S)-adamantan-1-yl 2-phenylacetate
• CAS NO: 40155-10-0
• Molecular Weight: 270.371
• Mol File: 40155-10-0.mol

Chemical Properties

• CAS DataBase Reference: (3S,5S,7S)-adamantan-1-yl 2-phenylacetate(CAS DataBase Reference)
• NIST Chemistry Reference: (3S,5S,7S)-adamantan-1-yl 2-phenylacetate(40155-10-0)
• EPA Substance Registry System: (3S,5S,7S)-adamantan-1-yl 2-phenylacetate(40155-10-0)

Safety Data

• Hazardous Substances Data: 40155-10-0(Hazardous Substances Data)

Upstream product

• 103-82-2 phenylacetic acid 
• 768-95-6 1-adamanthanol 
• 103-80-0 phenylacetyl chloride 
• 370-84-3 phenylacetyl fluoride 

Relevant articles and documents

Gram-Scale Preparation of Acyl Fluorides and Their Reactions with Hindered Nucleophiles

A series of acyl fluorides was synthesized at 100 mmol scale using phase-transfer-catalyzed halogen exchange between acyl chlorides and aqueous bifluoride solution. The convenient procedure consists of vigorous stirring of the biphasic mixture at room temperature, followed by extraction and distillation. Isolated acyl fluorides (usually 7-20 g) display excellent purity and can be transformed into sterically hindered amides and esters when treated with lithium amide bases and alkoxides under mild conditions.

Kinetic Analysis as an Optimization Tool for Catalytic Esterification with a Moisture-Tolerant Zirconium Complex

This work describes the use of kinetics as a tool for rational optimization of an esterification process with down to equimolar ratios of reagents using a recyclable commercially available zirconocene complex in catalytic amounts. In contrast to previously reported group IV metal-catalyzed esterification protocols, the work presented herein circumvents the use of water scavengers and perfluorooctane sulfonate (PFOS) ligands. Insights into the operating mechanism are presented.

Esterification of carboxylic acids with alcohols under microwave irradiation in the presence of zinc triflatet

The esterification of aliphatic and aromatic carboxylic acids with various alcohols (1°, 2°, 3°, benzylic) was studied under microwave irradiation in the presence of zinc triflate as catalyst; the reaction times were short and the yield of reactions was good to excellent.