401573-70-4Relevant academic research and scientific papers
Development of dirhodium(II)-catalyzed generation and enantioselective 1,3-dipolar cycloaddition of carbonyl ylides
Hodgson, David M.,Stupple, Paul A.,Pierard, Francoise Y. T. M.,Labande, Agnes H.,Johnstone, Craig
, p. 4465 - 4476 (2001)
Catalytic, enantioselective, tandem carbonyl ylide formation/cycloaddition of 2-diazo-3,6-diketoester 2 with the use of dirhodium tetrakiscarboxylate and tetrakisbinaphtholphosphate catalysts to give the cycloadducts 3 in good yields and up to 90% ee is described.
